Microplastics (MPs) are a growing environmental issue because of their widespread prevalence and their long-term effects on ecosystems and human health. Global studies have identified MPs in various aquatic environments, such as lake, rivers, estuaries, wastewater, and oceans. Although most MPs originate from urban surface water sources, the specific intensity, characteristics, and associated risk assessments remain unclear. This study focuses on west Godavari region of India, specifically analyzing MPs in surface water samples Godavari River and two water treatment plants (WTPs). A total of 330 MPs found in the surface water and 121 MPs in theWTP. In surface water, MPs were predominantly blue and transparent fibers, with the majority measuring less than 500 μm in size. Conversely, at the WTP, larger MPs, primarily in blue fiber form and exceeding 3000 μm, were observed. Additionally, μ-Raman spectroscopy analysis identified the presence of various polymers, including PP, PVC, PC, Nylon, and PET, among others. The risks associated with MPs, including their concentration and chemical composition, were assessed across all sample types using various indices such as Contamination Factor (CFi), Pollution Load Index (PLI), Polymer Risk Index (H), Potential Ecological Risk Index (RI), and Estimated Intake (EI) (daily, annually, and lifetime). The risk assessment revealed that the type of polymer poses a greater risk of MP pollution than the concentrations of MPs themselves. These findings provide critical insights into MP contamination patterns and risks, emphasizing the need for targeted mitigation strategies in this region.
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http://dx.doi.org/10.1016/j.jenvman.2025.124098 | DOI Listing |
Sci Rep
January 2025
Faculty of Civil Engineering and Geosciences, Delft University of Technology, 2628 CD, Delft, The Netherlands.
Laboratory experiments were performed to investigate the attenuation of progressive deep-water waves by a mono-layer of loose- and close-packed floating spheres. We measured the decay distance of waves having different incident wave frequency and steepness. The attenuation of waves was strong if the surface concentration of particles was close-packed, with the decay distance being shorter for incident waves with higher frequency and steepness.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Tianjin University, Department of Chemistry, #92, Weijin Road, Nankai District, Department of Chemistry, School of Science, Tianjin University, 300072, Tianjin, CHINA.
Electrocatalytic oxidation of cyclohexanol/cyclohexanonein water provides a promising strategy for obtaining adipic acid (AA), which is an essential feedstock in the polymer industry. However, this process is impeded by slow kinetics and limited Faradaic efficiency (FE) due to a poor understanding of the reaction mechanism. Herein, NiCo2O4/CeO2 is developed to enable the electrooxidation of cyclohexanol to AA with a 0.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
The University of Hong Kong, Department of Chemistry, Pokfulam Road, 999077, Hong Kong, CHINA.
Electrically conductive coordination polymers (ECCPs), particularly those incorporating benzenehexathiol (BHT) ligands, are emerging as a distinctive class of electronic materials with tunable semiconducting and metallic properties. However, the exploration of novel ECCPs with low-symmetry structures and electrical anisotropy remains under development. Here, we report the on-water surface synthesis of a novel ECCP, namely Cu5BHT, which exhibits a low-symmetry structure and unique in-plane electrical anisotropy that differs from the well-known Cu3BHT phase.
View Article and Find Full Text PDFSci Bull (Beijing)
January 2025
Beijing National Laboratory for Molecular Sciences, CAS Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Centre for Excellence in Molecular Sciences, Centre for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; School of Chemistry, University of Chinese Academy of Sciences, Beijing 100049, China; Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China. Electronic address:
Temperature affects both the thermodynamics of intermediate adsorption and the kinetics of elementary reactions. Despite its extensive study in thermocatalysis, temperature effect is typically overlooked in electrocatalysis. This study investigates how electrolyte temperature influences CO electroreduction over Cu catalysts.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh, 160014, India; Department of Applied Chemistry, Maulana Abul Kalam Azad University of Technology, Simhat, Haringhata, West Bengal, 741249, India. Electronic address:
Background: The intellectual progress in fabricating artificial probes for selective appraisal of biologically admissible amino acids has displayed exponential growth in recent era.The neoteric era in material science has witnessed the significant application of carbon quantum dots (CQDs). However, the hybrid microgel of CQDs was less explored.
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