Electrocatalytic methane conversion via in-situ generated superoxide radicals in an aprotic ionic liquid.

The electrochemical activation and partial oxidation of methane are highly attractive to enable the direct conversion in a sustainable and decentralized way. Herein, we report an electrochemical system in a non-diaphragm electrochemical bath to convert CH to CHOH and CHCHOH at room temperature, in which VO·HO as the anodic catalyst to activate CH and an aprotic ionic liquid [BMIM]BF as supporting electrolyte to control superoxide radicals (O) as the main active oxygen species generated on cathode. As a result, methanol and ethanol were identified as the liquid products, and the superior methanol Faraday efficiency (FE) of 32.2 % and selectivity of 76.8 % can be reached. Molecular dynamics (MD) simulation indicates that interaction between CH molecules and [BMIM]BF, which enhances the mass transfer in electrochemical reaction. Density function theory (DFT) calculation results suggest that the V sites in VO·HO enhanced the chemisorption and dissociation of CH molecules on anode surface, then superoxide radicals (O) are supposed to be involved in the formation of methanol and ethanol.