A finite element model of the local mechanical response of a filled polymer composite to uniaxial compression is presented. The interfacial layer between filler particles and polymer matrix is explicitly modeled as a third phase of the composite. Unit cells containing one or several anisometric filler particles surrounded by interface shells are considered. The dependence of the mechanical response of the cells to external deformation on the interface thickness and stiffness is studied. The use of the particle-matrix interface as a damping tool in mesoscopic polymer-composite problems with large deformations is discussed. The influence of the interface on the anisotropy of the composite response is considered.
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http://dx.doi.org/10.3390/polym17010111 | DOI Listing |
Polymers (Basel)
January 2025
Faculty of Physics, Lomonosov Moscow State University, Moscow 119991, Russia.
A finite element model of the local mechanical response of a filled polymer composite to uniaxial compression is presented. The interfacial layer between filler particles and polymer matrix is explicitly modeled as a third phase of the composite. Unit cells containing one or several anisometric filler particles surrounded by interface shells are considered.
View Article and Find Full Text PDFNanoscale
January 2025
Department of Chemistry, Manipal University Jaipur, Jaipur-303007, Rajasthan, India.
Polyvinyl alcohol (PVA) is a well-known and cost-effective synthetic polymer that offers a variety of applications, including medical, food, aerospace, automotive, and material industries, for the construction of structures. However, the weak adhesion, low wear resistance, and mechanical properties of PVA usually limit their functionality and durability. Herein, the strength and bonding of the polymeric matrix were enhanced by metallization and reinforcement of carbonaceous allotropes.
View Article and Find Full Text PDFGels
October 2024
Departamento de Polímeros, Facultad de Ciencias Químicas, Universidad de Concepción, Concepción 4030000, Chile.
Geological formations have superior wickability and support the absorption of water and oils into narrow spaces of Earth's crust without external assistance. In this study, we present speleothem inspired heterogeneous porous and wicked copper (Cu)/nickel (Ni) interfaces for enhanced nucleate boiling of water/ethanol mixtures for energy-efficient separation processes. The incorporation of Ni strands within the copper particle matrix significantly enhanced heat transfer.
View Article and Find Full Text PDFACS Omega
February 2024
Composites Research Network-Okanagan Laboratory, School of Engineering, University of British Columbia, Kelowna, British Columbia V1V 1V7, Canada.
Biopolymer blends have attracted considerable attention in industrial applications due to their notable mechanical properties and biodegradability. This work delves into the innovative combination of butadiene-acrylonitrile (referred to as NBR) with a pectin-based biopolymer (NGP) at a 90:10 mass ratio through a detailed analysis employing mechanical characterization, Fourier transform infrared (FTIR) analysis, thermogravimetric analysis (TGA), and morphology studies using SEM. Additionally, biopolymer's biodegradability under aerobic and anaerobic conditions is tested.
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