Performance Evaluation of Enhanced Oil Recovery by Host-Guest Interaction of β-Cyclodextrin Polymer/Hydrophobically Associative Polymer.

Molecules

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, China.

Published: December 2024

AI Article Synopsis

  • A hydrophobically associative polymer (HAP) was combined with β-cyclodextrin and epichlorohydrin polycondensate (β-CDP) to boost intermolecular interactions in water, improving thickening and viscoelastic properties.
  • The resulting host-guest inclusion system showed unique viscosity-temperature characteristics and variable activation energy, enhancing the solution's performance in oil recovery applications.
  • Tests indicated that the β-CDP/HAP mixture outperformed pure HAP and other solutions, achieving a 5.5% and 9.3% greater oil recovery than HAP and a partially hydrolyzed polyacrylamide solution, respectively, making it more effective for high-temperature oil extraction.

Article Abstract

In this work, a hydrophobically associative polymer (HAP) was mixed with β-cyclodextrin and epichlorohydrin polycondensate (β-CDP) in an aqueous solution to enhance the intermolecular interaction through host-guest inclusion between hydrophobes and cyclodextrins. Results showed that the host-guest interaction improved the thickening ability and viscoelasticity of the HAP solution and maintained its shear thinning behavior. The host-guest inclusion system demonstrated special viscosity-temperature curves and variable activation energy. Enhanced oil recovery (EOR) performance tests showed that the oil increment produced by the host-guest inclusion system was 5.5% and 9.3% higher than that produced by the HAP and the partially hydrolyzed polyacrylamide solution, respectively. Compared with pure HAP, β-CDP/HAP has a better comprehensive performance and is more attractive for EOR in high-temperature reservoirs.

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Source
http://dx.doi.org/10.3390/molecules30010109DOI Listing

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