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Synthesis of an Azido-Substituted 8-Membered Ring Laddersiloxane and Its Application in Catalysis.
Molecules
January 2025
ICGM, Univ Montpellier, CNRS, ENSCM (Institut Charles Gerhardt Montpellier, Université de Montpellier, Centre National de la Recherche Scientifique, École Nationale Supérieure de Chimie de Montpellier), 1919 Route de Mende, CEDEX 05, 34293 Montpellier, France.
A first -type tricyclic 8-8-8 (three fused-8-membered ring) laddersiloxane functionalized with four azido groups was successfully synthesized through efficient and highly selective hydrosilylation and nucleophilic substitution, achieving an excellent overall yield. The starting material, a tetravinyl-substituted 8-8-8 laddersiloxane, was prepared via a straightforward and scalable method. The obtained azido-functionalized ladder compound, fully characterized, constitutes a versatile building block for hybrid materials.
View Article and Find Full Text PDFThe Influence of Rice Husk Ash Incorporation on the Properties of Cement-Based Materials.
Materials (Basel)
January 2025
Green Environmental Protection Industry Co., Ltd., Guiyang 551109, China.
Rice husk ash is a kind of biomass material. Its main component is silicon dioxide, with a content of up to 80%. It has high pozzolanic activity and can react with hydroxide in cement.
View Article and Find Full Text PDFMechanistic Insights into CO Adsorption of LiSiO at High Temperature.
Materials (Basel)
January 2025
Hunan Key Laboratory of Applied Environmental Photocatalysis, School of Materials and Environmental Engineering, Changsha University, Changsha 410022, China.
The development of materials with high adsorption capacity for capturing CO from industrial exhaust gases has proceeded rapidly in recent years. LiSiO has attracted attention due to its low cost, high capture capacity, and good cycling stability for direct high-temperature CO capture. Thus far, the CO adsorption mechanism of LiSiO is poorly understood, and detailed phase transformations during the CO adsorption process are missing.
View Article and Find Full Text PDFNutritional and Microbiome Effects of a Partial Substitution of Poultry Meat with Hydrolyzed Feather Meal in Dog Diets.
Microorganisms
January 2025
Department of Veterinary Sciences, University of Messina, Via Palatucci Snc, 98168 Messina, Italy.
Two extruded diets isoenergetic, isonitrogenous, and isolipidic were formulated with poultry meal (control diet) as the source of animal-origin proteins (160 g/kg of feed) or with 90 g/kg of poultry meal and 70 g/kg of hydrolyzed feather meal (treated diet) and were fed to eight dogs (four adult female and four adult male English Setters). Body condition, muscle condition, and fecal consistency scores and body weight were monitored at the beginning of the trial and after 3, 7, 15, and 45 days, and no significant differences ( > 0.05) were observed between diets and between sex.
View Article and Find Full Text PDFPreventive effects of thymoquinone on glyco-nitro-oxidized human fibrinogen: A comprehensive biophysical study projecting possible therapeutic role in diabetes and associated complications.
Int J Biol Macromol
January 2025
Department of Biochemistry, Jawaharlal Nehru Medical College, Faculty of Medicine, Aligarh Muslim University, Aligarh, Uttar Pradesh, India. Electronic address:
Persistence of long-term hyperglycemia results in the glyco-oxidation of plasma proteins, which is considered to be a significant factor in metabolic dysfunction, linking hyperglycemia to the emergence of vascular complications. Methylglyoxal (MGO), a dicarbonyl species formed excessively under diabetes, elevates the oxidative stress, enhancing the generation of superoxide anion, which ultimately reacts with nitric oxide (NO•) to form peroxynitrite (PON). PON, being a powerful nitro-oxidizing agent distorts protein structure, hampering its function.
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