Facile Aqueous Route to Large-Scale Superhydrophilic TiO-Incorporated Graphitic Carbon Nitride-Coated Ni(OH) and NiP Nano-Architecture Arrays as Efficient Electrocatalysts for Enhanced Hydrogen Production.

Water splitting by an electrochemical method to generate hydrogen gas is an economic and green approach to resolve the looming energy and environmental crisis. Designing a composite electrocatalyst having integrated multichannel charge separation, robust stability, and low-cost facile scalability could be considered to address the issue of electrochemical hydrogen evolution. Herein, we report a superhydrophilic, noble-metal-free bimetallic nanostructure TiO/NiP coated on graphitic polyacrylonitrile carbon fibers (g-C/TiO/NiP) using a facile hydrothermal method followed by phosphorylation. In an aqueous-based route, PAN is dissolved in water in the presence of ZnCl, followed by wet-spinning to prepare scalable PAN/ZnCl fibers. The nitrogen-contained porous graphitic carbon fibers are prepared via the pyrolysis of PAN/ZnCl fibers; now ZnCl acts as a volatile porogen to form porous matrix structures. Finally, the as-prepared graphitic carbon fibers are electrochemically activated by incorporating TiO/NiP active sites. The materials formed in this work show excellent electrocatalytic activity for the hydrogen evolution reaction. The as-synthesized g-C/TiO/NiP catalyst shows a low overpotential, its electrocatalytic activity is improved, and its efficiency is better than that of the commercial Pt/C catalyst. At a current density of -10 mA/cm, the g-C/TiO/NiP catalyst shows an overpotential of 55 mV, while the commercial Pt/C catalyst shows an overpotential of 77 mV. Our work provides a facile aqueous scalable route with no need for noble metals that can be considered as a potential alternative for the commercial Pt/C catalyst.