The title compound is a germanium-based hybrid metal halide that represents a less-toxic alternative to more popular lead-based analogues in optoelectronic applications. {(2-ICHNH)[GeI]} is composed of infinite inorganic layers that are formed by [GeI] octa-hedra connected in a corner-sharing manner with four equatorial I atoms. The organic (2-ICHNH) cations inter-leave the inorganic layers. There are two types of 2-iodo-ethyl-ammonium cations, with synclinal and anti-periplanar conformations. The organic cations inter-act with the inorganic layers through hydrogen bonds and I⋯I contacts. The crystal under investigation was twinned by a 180° rotation around [100].
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11701769 | PMC |
| http://dx.doi.org/10.1107/S2056989024011800 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
A biofuel cell of (methyl violet/AuNPs)/FTO photoanode and bilirubin oxidase/CuCoO bio-photocathode inspired by the photoelectrochemistry activities of fluorescent materials/molecules.
RSC Adv
January 2025
Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education of China), College of Chemistry and Chemical Engineering, Hunan Normal University Changsha 410081 China
Herein, we discuss the idea that fluorescent materials/molecules should logically show potential photoelectrochemistry (PEC) activity, and, in particular, the PEC of fluorescent small molecules (previously usually acting only as dye sensitizers for conventional semiconductors) is explored. After examining the PEC activities of some typical inorganic or organic fluorescent materials/molecules and by adopting methyl violet (MV) with the highest PEC activity among the examined fluorescent small molecules, a new and efficient (MV/Au nanoparticles (AuNPs))/fluorine-doped tin oxide (FTO) photoanode without conventional semiconductor(s) is prepared by layer-by-layer alternating the electrodeposition of AuNPs and the adsorption of MV. A bilirubin oxidase (BOD)/CuCoO/FTO bio-photocathode is prepared by electrodeposition, calcination and cast-coating.
View Article and Find Full Text PDFSelf-Assembled Monolayer-Functionalized NiO Hole Injection layer for Improved Charge Injection in Quantum Dot Light-Emitting Diodes.
ACS Appl Mater Interfaces
January 2025
School of Materials Science and Engineering, Kyungpook National University, Daegu 41566, Republic of Korea.
The development of quantum dot light-emitting diodes (QLEDs) represents a promising advancement in next-generation display technology. However, there are challenges, especially in achieving efficient hole injection, maintaining charge balance, and replacing low-stability organic materials such as PEDOT:PSS. To address these issues, in this study, self-assembled monolayers (SAMs) were employed to modify the surface properties of NiO, a hole injection material, within the structure of ITO/HIL/TFB/QDs/ZnMgO/Al QLEDs.
View Article and Find Full Text PDFSynergistic enhancement of high-barrier polylactic acid packaging materials by various morphological carbonized cellulose nanocrystals.
Carbohydr Polym
March 2025
Key Laboratory of Intelligent Textile and Flexible Interconnection of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou 310018, China. Electronic address:
The environmental challenges linked to petroleum-based polymers have accelerated the search for alternative materials like polylactic acid (PLA). Diverse nanofillers, ranging from inorganic to organic and hybrid inorganic/organic varieties, are employed to bolster PLA performance. Yet, non-synergistic nanofillers often underperform due to inadequate dispersion and singular functionality within the PLA matrix.
View Article and Find Full Text PDFFrom Marine Debris to a Valuable Medical Resource: A review on biology, chemistry, ethnopharmacology, bioactivity and application in biomedical materials of Cuttlebone.
J Ethnopharmacol
January 2025
Key Laboratory of Basic and Application Research of Beiyao, Heilongjiang University of Chinese Medicine, Ministry of Education, Harbin, 150040, China. Electronic address:
Ethnopharmacological Relevance: Cuttlebone (CB), also known as SEPIAE ENDOCONCHA, is the inner shell of cuttlefish and has been employed in traditional medicine in numerous countries since antiquity. Despite its significant medicinal value, CB is often underestimated and discarded on the beach as debris in some countries, which considerably impacts the environment and economy.
The Aim Of The Review: This study aims to elucidate the value of CB, particularly in the context of its medicinal properties, to promote its rational utilization.
Retention mechanism on phosphodiester stationary phases in HILIC and purely aqueous mobile phase, Part I: The problem of hold-up volume determination.
J Chromatogr A
December 2024
HUN-REN Molecular Interactions in Separation Science Research Group, Ifjúság útja 6, H-7624 Pécs, Hungary; Department of Analytical and Environmental Chemistry and Szentágothai Research Center, University of Pécs, Ifjúság útja 6, H-7624 Pécs, Hungary; Institute of Bioanalysis, Medical Scool, University of Pécs, Szigeti út, H-7624 Pécs, Hungary. Electronic address:
Non-destructive chromatographic methods were used to determine the hold-up volumes of four self-packed columns containing embedded phosphate groups. The stationary phases are named Diol-P-C10, Diol-P-C18, Diol-P-Benzyl and Diol-P-Chol. The hydrophobicity of organic ligands bound to the phosphate group increases in the benzyl< decyl < octadecyl
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!