The oscillatory Belousov-Zhabotinsky (BZ) reaction is often used for the study of rotating spiral waves that are responsible for life-threatening cardiac arrhythmia. In this work, we explore the influence of a concentration gradient on the dynamics of spiral waves in the BZ-reaction system. Using ion-exchange resin beads, we introduce a gradient of hydrogen ions in a thin layer of BZ gel hosting a spiral wave. By monitoring the drift of the spiral tips from their initial position, we show that a gradient of hydrogen-ions can manoeuvre the position of the spiral. The magnitude of the drift is found to depend on the gradient strength and relative position of the spiral from the resin beads. Our experimental study is supported with numerical simulations carried out on a modified Oregonator model that we have developed from the Field, Körös, Noyes mechanism of the BZ.
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http://dx.doi.org/10.1039/d4cp03734k | DOI Listing |
J Fish Biol
January 2025
Laboratory of Ecophysiology and Molecular Evolution, Brazilian National Institute for Research of the Amazon (INPA), Manaus, Brazil.
The tambaqui (Colossoma macropomum, G. Cuvier 1818) thrives both in the ion-poor waters of the Amazon and in commercial aquaculture. In both, environmental conditions can be harsh due to low ion levels, occasional high salt challenges (in aquaculture), low pH, extreme PO levels (hypoxia and hyperoxia), high PCO levels (hypercapnia), high ammonia levels (in aquaculture), and high and low temperatures.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
Key Laboratory of Jianghuai Agricultural Product Fine Processing and Resource Utilization, Ministry of Agriculture and Rural Affairs, Anhui Engineering Research Center for High Value Utilization of Characteristic Agricultural Products, School of Tea & Food Science and Technology, Anhui Agricultural University, Hefei 230036, China. Electronic address:
This research investigated the effect modified solvent-shifting method on the formation, ordered structure, and morphology of V-type starch. Ionic liquid (IL) dissolution and hot ethanol aqueous incubation in gradient concentrations from 30 % to 80 % (v/v) were applied to optimize the relative crystallinity of V-type starch. The results showed that this new method worked in producing V-type conformation, and higher ethanol concentration tended to yield V-type starch with higher crystallinity and more disk-like shape structure within the ethanol range of 30-50 % (v/v).
View Article and Find Full Text PDFEnviron Pollut
January 2025
Xi'an Center of Mineral Resources Survey, China Geological Survey, Xi'an, China.
Understanding the geochemical mechanisms governing hexavalent chromium (Cr(VI)) in groundwater is essential for mitigating health risks. However, the processes driving Cr(VI) accumulation and migration in loess regions remain insufficiently understood. This study investigated the occurrence, release, and migration mechanisms of Cr(VI) across different groundwater environmental units (GEUs) in the south-central Loess Plateau, China.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
UMR1114 EMMAH INRAE-AU, 228, Route de L'Aérodrome, Avignon, F84000, France. Electronic address:
Hypothesis: Water drop infiltration into a thin amphiphilic porous medium is influenced by wettability. Due to the reorganization of amphiphilic matter in contact with water, polar interaction changes the wettability in the bulk porous medium and at the liquid/porous substrate interface. To model out of equilibrium water transfer, we propose a thermodynamics approach derived from Onsager's principle.
View Article and Find Full Text PDFJ Pharm Biomed Anal
January 2025
Jiangsu Key Laboratory of New Drug Research and Clinical Pharmacy, Xuzhou Medical University, Xuzhou 221004, China; Department of Pharmacy, Suining People's Hospital Affiliated to Xuzhou Medical University, Suining 221202, China; Department of Pharmaceutical Analysis, Xuzhou Medical University, Xuzhou 221204, China. Electronic address:
Currently, treatment with antiepileptic drugs (AEDs) is still the first choice for epileptic patients, while monitoring their blood concentrations is undoubtedly beneficial for minimizing their adverse side effects and optimizing their therapeutic effects. In this study, an ultra-high performance liquid chromatography coupled with tandem mass spectrometry with polarity switching was developed and validated for simultaneous determination of 14 AEDs and 2 active metabolites in human serum. Olanzapine was selected as the internal standard.
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