Methane gas leakage can lead to pollution problems, such as rising ambient temperature. In this paper, the Vernier effect of a double D-shaped photonic crystal fiber (PCF) in a Sagnac interferometer (SI) is proposed for the accurate detection of mixed methane gas content in the gas. The optical fiber structure of the effective sensing in the sensing SI loop and the effective sensing in the reference SI loop are the same. Both of them adopt the polarization-maintaining photonic crystal fiber (PM-PCF) designed in this paper. The optical fiber structure of the effective sensing in the sensing SI loop deposited with the methane gas-sensitive film is polished to obtain a double-D structure. This operation makes it easier for methane gas to contact the sensitive film and realize the sensor's repeated use. The sensing capability of the methane gas sensor was evaluated utilizing the finite element method (FEM). The numerical simulation results show that when the concentration of methane gas in the environment is 0~3.5%, the average sensitivity of two parallel Sagnac loops is 409.43 nm/%. Using Vernier effect cascade SI loops, the sensitivity of the sensor for detecting methane gas increased by four times. Without considering air and humidity, we provide a practical scheme for the development and design of high-sensitivity methane gas sensors.
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http://dx.doi.org/10.3390/s24248132 | DOI Listing |
Chemistry
January 2025
Fujian Normal University, School of Chemistry and Materials, No.8 Shangsan Road, ., Fuzhou City, CHINA.
The advancement of high-value CH4 purification technology within the natural gas industry is paramount for industrial processes. Herein, we constructed ZJNU-402, a new porous material characterized by permanent porosity, as an effective adsorbent for separating C3H8/CH4 and C2H6/CH4 mixtures. The findings reveal an outstanding C3H8 adsorption capacity of 68 cm3 g-1 and a moderate C2H6 adsorption rate of 42 cm3 g-1, with a notably lower CH4 adsorption rate of 11 cm3 g-1.
View Article and Find Full Text PDFPLoS One
December 2024
Environmental Molecular Sciences Division, Pacific Northwest National Laboratory, Richland, Washington, United States of America.
Coastal wetlands, including freshwater systems near large lakes, rapidly bury carbon, but less is known about how they transport carbon either to marine and lake environments or to the atmosphere as greenhouse gases (GHGs) such as carbon dioxide and methane. This study examines how GHG production and organic matter (OM) mobility in coastal wetland soils vary with the availability of oxygen and other terminal electron acceptors. We also evaluated how OM and redox-sensitive species varied across different size fractions: particulates (0.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Laboratory of Theoretical Biophysics, School of Physical Science and Technology, Inner Mongolia University, Hohhot 010021, China.
The formation of natural gas hydrates presents significant economic and safety challenges to the petroleum and gas industry, necessitating the development of effective prevention strategies. This study investigates an environmentally sustainable Tenebrio molitor antifreeze protein (TmAFP) modified to be a potential kinetic hydrate inhibitor. The aim of this study was to enhance the inhibitory activity of TmAFP by systematically substituting threonine (Thr) residues with glycine (Gly), alanine (Ala), or serine (Ser) at positions 29, 39, and 53.
View Article and Find Full Text PDFmBio
January 2025
Department of Microbiology, University of Illinois Urbana-Champaign, Champaign, Illinois, USA.
Methyl-coenzyme M reductase (MCR), the key catalyst in the anoxic production and consumption of methane, contains an unusual 2-methylglutamine residue within its active site. data show that a B12-dependent radical SAM (rSAM) enzyme, designated MgmA, is responsible for this post-translational modification (PTM). Here, we show that two different MgmA homologs are able to methylate MCR when expressed in , an organism that does not normally possess this PTM.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
January 2025
Department of Chemical Engineering, Stanford University, Stanford, CA 94305.
High degree of fluorination for ether electrolytes has resulted in improved cycling stability of lithium metal batteries due to stable solid electrolyte interphase (SEI) formation and good oxidative stability. However, the sluggish ion transport and environmental concerns of high fluorination degree drive the need to develop less fluorinated structures. Here, we depart from the traditional ether backbone and introduce bis(2-fluoroethoxy)methane (F2DEM), featuring monofluorination of the acetal backbone.
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