Biopolymers are promising sustainable alternatives to petrochemical polymers, but the recent increase in published research articles has not translated into marketable products. Here, we discuss barriers to market entry by exploring application-specific, ecological, and economic aspects, such as the utilization of biodegradable polymers to mitigate the accumulation of microplastics. We summarize previous studies revealing how fiber surface properties and the dwell time during fiber spinning affect degradability. We show how biopolymers can be processed on existing machines and how degradability can be tailored by changing process parameters. This novel approach, known as degradation by design, will allow us to rethink product development and ensure that biopolymers are not only able to replace petrochemical polymers but also reduce the environmental harm they cause.
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http://dx.doi.org/10.3390/polym16243498 | DOI Listing |
Polymers (Basel)
December 2024
Department of Mechanical Engineering, PSG Institute of Technology and Applied Research Coimbatore, Coimbatore 641062, India.
In this work, twin-screw extruder and compression moulding techniques were utilized to fabricate polymer blends: polypropylene (PP), polybutadiene (PB), and composites using glass fibre (GF) and flax fibre (FF). During fabrication, the polymer ratios maintained between PP and PB were 90:10, 80:20, and 70:30. Likewise, the composites were fabricated by varying the ratios between the PP, PB, and GF, which were 90PP:10PB:10GF, 80PP:20PB:10GF, and 70PP:30PB:10GF.
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December 2024
School of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing 211167, China.
In this study, CO reacted with a curing agent through nucleophilic addition to form ammonium salts, enabling the stable capture and internal release of CO, which achieved gas-phase nucleation and foaming. Additionally, the introduction of wave-absorbing agents improved the absorption mechanism and promoted uniform foaming. This nucleation-free foaming process relies on the induced growth of gas nuclei and the synergistic effect of the wave-absorbing agents, effectively preventing the uneven foaming issues caused by traditional nucleating agents.
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December 2024
A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Prospect 29, 119991 Moscow, Russia.
The pervaporation properties of membranes based on comb-like polysiloxanes when C-C alcohols are removed from water were studied for the first time. It was established that membranes based on comb-like polysiloxanes with linear aliphatic and organosilicon substituents have increased permeability selectivity for C alcohols. The obtained results were interpreted from the point of view of the solubility of the components of the separated mixture in polysiloxanes.
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December 2024
Meat Technology & Science of Protein-Rich Foods (MTSP), Department of Microbial and Molecular Systems, Leuven Food Science and Nutrition Research Centre, KU Leuven Campus Ghent, B-9000 Ghent, Belgium.
The valorization of potato peel side streams for food packaging applications, especially for the substitution of current petrochemical-based oxygen barrier solutions such as EVOH, is becoming increasingly important. Therefore, potato peel-based films and coatings (on PLA) were developed containing 10-50% (/ potato peel) citric acid (CA). To determine the impact of CA concentration on the structure and physicochemical properties of cast films and coatings, ATR-FTIR spectroscopy, moisture adsorption isotherms, tensile properties, light transmittance, oxygen permeability, carbon dioxide transmission rate, and water vapor transmission rate measurements were performed.
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December 2024
Green and Sustainable Materials R&D Department, Korea Institute of Industrial Technology (KITECH), Cheonan 31056, Republic of Korea.
Recent advancements in polymer materials have enabled the synthesis of bio-based monomers from renewable resources, promoting sustainable alternatives to fossil-based materials. This study presents a novel zwitterionic surfactant, SF, derived from 10-undecenoic acid obtained from castor oil through a four-step reaction, achieving a yield of 78%. SF has a critical micelle concentration (CMC) of 1235 mg/L, slightly higher than the commercial anionic surfactant Rhodacal DS-4 (sodium dodecyl benzene sulfonate), and effectively stabilizes monomer droplets, leading to excellent conversion and stable latex formation.
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