The potential of blue light (BL) and sous-vide (S-V) as a novel approach for food preservation was investigated via measurements of the total phenolic content (TPC), antioxidative activity, color, and their antibacterial effect on in two versions of laboratory-prepared kale pesto, with and without the addition of turmeric. The TPC ranged from 85 to 208 mg/100 g GAE d.m. and 57 to 171 mg/100 g GAE d.m., respectively. In both versions, the highest TPC was in the blue light-sous-vide samples, while the lowest was after the sous-vide, with a loss of polyphenols of almost 40% during storage when turmeric was absent. Antioxidative capabilities of the pesto were initially estimated at 54.07 and 7.46 µmol TE/g d.m., respectively, indicating significant bioactivity enhancement by turmeric. In turmeric-enriched pesto, sous-vide decreased the antioxidative activity levels by 12% in fresh pesto and by 45% during storage. Meanwhile, blue light compensated for the losses caused by the sous-vide treatment. Although the hue angle (°) of sous-vide pesto was lower than that of blue light pesto in most samples, sequential BL and S-V ultimately yielded the lowest °. The sequential BL and S-V treatment resulted in a 1.7 log reduction in the population, whereas adding turmeric increased the treatment efficacy by another 2.0 logs. Thus, as a source of photosensitizing molecules, turmeric was highly antibacterial after photothermal activation with blue light and sous-vide. This study suggests that blue light could be an effective (pre)treatment used on pesto sauces to preserve bioactivity and to improve safety when enriched with a natural additive like turmeric.
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http://dx.doi.org/10.3390/molecules29245831 | DOI Listing |
Chemphyschem
January 2025
Friedrich-Schiller-University Jena, Institute of Physical Chemistry, Helmholtzweg 4, 7743, Jena, GERMANY.
The design and development of particulate photocatalysts has been an attractive strategy to incorporate earth-abundant metal ions to water splitting devices. Herein, we synthesized CoFe-Prussian blue (PB) coated ZnO origami core-shell nanostructures (PB@ZnO) with different mass ratio of PB components and investigated their photocatalytic water oxidation activities in the presence of an electron scavenger. Photocatalytic experiments reveal that the integration of PB on ZnO boosts the oxygen evolution rate by a factor of ~2.
View Article and Find Full Text PDFJ Orthop Res
January 2025
Department of Orthopaedic Surgery, Division of Arthroplasty and Joint Reconstruction, Brigham and Women's Hospital, Harvard Medical School, Boston, Massachusetts, USA.
Drug-resistant organisms (DROs) necessitate the development of new therapies. Antimicrobial blue light (ABL) is a promising option, utilizing photoexcitation of endogenous bacterial components to generate reactive oxygen species, leading to bacterial death. The aim of this study is to investigate the effects of a novel isotropic optical fiber under in-vitro conditions on multidrug-resistant gram-negative Pseudomonas aeruginosa (MDR-Pa) and methicillin-resistant Staphylococcus aureus (MRSA).
View Article and Find Full Text PDFChemistry
January 2025
Nanjing University of Posts and Telecommunications, Institute of Advanced Materials (IAM), 9 Wenyuan Road, Nanjing 210023, China., Nanjing, CHINA.
Circularly polarized organic light-emitting diodes (CP-OLEDs) have significant promise for naked-eye 3D displays. However, most devices are fabricated using vacuum deposition technology, and development of efficient solution-processed CP-OLEDs, particularly those exhibiting low efficiency roll-off, remains a formidable challenge. This research successfully designed and synthesized two pairs of thermally activated delayed fluorescence (TADF) enantiomers through isomer engineering, namely (R/S)-N-5-TPA and (R/S)-N-4-TPA, which features fifth and fourth substitution sites of phthalimide (acceptor) by tri-phenylamine (donor), respectively.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
School of Applied Sciences, Centurion University of Technology and Management, Bhubaneswar, Odisha, India.
Contamination of water resources by artificial coloring agents and the increasing incidence of bacterial illnesses are two significant environmental and public health issues that are getting worse day by day. Traditional treatment techniques frequently fail to address these problems adequately in a sustainable and environmental friendly way. In response, our study presents a novel photocatalyst that demonstrates superior photodegradation capability and antibacterial qualities in catering the above issues.
View Article and Find Full Text PDFNat Commun
January 2025
College of Chemistry, Beijing Normal University, Beijing, 100875, P.R. China.
Developing donor-acceptor [n]cycloparaphenylenes (D-A [n]CPPs) with multiple emissions from different emissive states remains challenging yet crucial for achieving white-light emission in single-molecule. Here, we report our explorations into acceptor engineering of quinone-based D-A [10]CPPs (Nq/Aq/Tq[10]CPPs) via a post-lateral annulation using Diels-Alder reactions of oxTh[10]CPP. X-ray analysis reveals that Nq[10]CPP displays a side by side packing via naphthoquione stacking while Aq[10]CPP adopts an intercalated conformation through anthraquinone interaction.
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