Photocatalytic hydrogen evolution using inexhaustible clean solar energy is considered as a promising strategy. In order to build an efficient photocatalytic hydrogen production system to satisfy the demands of practical applications, it is of great significance to design photocatalysts that offer high activity, low cost, and high stability. Herein, a series of cheap CdS/Ni(OH) composite photocatalysts were designed and synthesized using the hydrothermal method. The introduction of a Ni(OH) cocatalyst multiplied the reactive active site of cadmium sulfide and promoted the transfer of photoinduced electrons in a semiconductor. Therefore, CdS/Ni(OH) composites demonstrate significantly better photocatalytic performance, and the hydrogen production rate of an optimal CdS/5%Ni(OH) composite is 6.9 times higher than that of blank CdS. Furthermore, the stability test also showed that CdS/Ni(OH) had good stability. This study aims to serve as a rewarding reference for the development of high-performance composite photocatalysts.
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http://dx.doi.org/10.3390/molecules29245821 | DOI Listing |
Nat Commun
January 2025
Department of Chemical and Biological Sciences, S. N. Bose National Centre for Basic Sciences, Kolkata, 700106, India.
The conversion of solar energy into chemical energy or high-value chemicals has attracted considerable research interest in the context of the global energy crisis. Hydrogen peroxide (HO) is a versatile and powerful oxidizing agent widely used in chemical synthesis and medical disinfection. HO also serves as a clean energy source in fuel cells, generating electricity with zero-carbon emissions.
View Article and Find Full Text PDFEnviron Res
January 2025
College of Civil Engineering, Hefei University of Technology, Hefei, 238000, China; Chinaland Solar Energy Co., Ltd., Hefei, 238000, China. Electronic address:
The preparation strategy is the important factor to obtain the effective photocatalyst, and the thermal decomposition could be used to prepare photocatalysts with high crystallinity and photoactivity. In this paper, thermal decomposition method was used to deposit CuO nanoparticles on TiO nanotube arrays (TiO NTs), and the TiO NTs/CuO exhibited remarkably high visible light absorption and photoelectrocatalytic performances toward dye degradation and Cr(VI) reduction. The potential degradation pathway and toxicities of rhodamine B (RhB) dyes and intermediates were investigated.
View Article and Find Full Text PDFSmall
January 2025
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Haiquan Road, Shanghai, 201418, China.
How to improve the stability and activity of metal-organic frameworks is an attractive but challenging task in energy conversion and pollutant degradation of metal-organic framework materials. In this paper, a facile method is developed by fabricating titanium dioxide nanoparticles (TiO NPs) layer on 2D copper tetracarboxylphenyl-metalloporphyrin metal-organic frameworks with zinc ions as the linkers (ZnTCuMT-X, "Zn" represented zinc ions as the linkers, the first "T" represented tetracarboxylphenyl-metalloporphyrin (TCPP), "Cu" represented the Cu coordinated into the porphyrin macrocycle, "M" represented metal-organic frameworks, the second "T" represented TiO NPs layer, and "X" represented the added volume of n-tetrabutyl titanate (X = 100, 200, 300 or 400)). It is found that the optimized ZnTCuMT-200 showed greatly and stably enhanced H generation, which is ≈28.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Tianjin University of Technology, Institute for New Energy Materials and Low Carbon Technologies, 300384, Tianjin, CHINA.
Porous supramolecular crystalline materials (PSCMs), usually including hydrogen-bonded organic frameworks (HOFs), π frameworks, and so on, can be defined as a type of porous supramolecular assemblies stabilized by hydrogen-bonding, π-π stacking and other non-covalent interactions. Given the unique features of mild synthetic conditions, well-defined and tailorable structures, easy healing and regeneration, PSCMs have captured widespread interest in molecular recognition, sensor, gas storage and separation, and so on. Moreover, they currently emerge as promising photocatalysts because it is readily to endow PSCMs with photo-function, and the hydrogen-bonding and π-π stacking can serve as electron transfer channels to boost photocatalytic activity.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
South China Normal University, school of chemistry, No. 378, Waihuan West Road, Panyu District, 510006, Guangzhou, CHINA.
In this work, a series of new crystalline three-dimensional covalent organic frameworks (3D COFs) based on [8+4] construction was designed and successfully realized efficient photocatalytic acetylene (C2H2) hydrogenation to ethylene (C2H4). By regulating the hydrogen-localization transfer effect in these 3D COFs,the Cz-Co-COF-H containing cobalt glyoximate active centers exhibited excellent C2H2-to-C2H4 performance, with an average C2H4 yield of 1755.33 μmol g-1 h-1 in pure C2H2, also showed near 100% conversion of C2H2 in 1% C2H2 contained crude C2H4 mixtures (industry-relevant conditions), and finally obtain polymer grade C2H4.
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