The aim of the presented research was to evaluate the impacts of modifications to the technical properties of fly ash-based geopolymer composites, particularly focusing on enhancing the thermal insulation. Through the utilization of a generalized utility function, optimal dosages of additives such as perlite sand, waste perlite powder, and cenospheres were determined. The study aimed to increase the thermal insulation of the composites while maintaining satisfactory compressive and flexural strength. The results indicated that dosages of perlite dust and cenospheres significantly influenced the technical characteristics of the composites; an exception was the flexural strength, for which these modifications did not show a statistically significant effect. The average compressive strength values, except for the mixes with poor workability, were at least 3.5 MPa (RILEM class II). Notably, a balanced dosage of additives, around 75 kg per cubic meter of the mixture in the total mixture, yielded the most favorable outcomes in terms of thermal isolation (0.18-0.24 W/(m·K) and workability (cone immersion 40-70 mm). Additionally, perlite dust emerged as a potentially superior modifier due to its waste origin. However, further analysis considering life cycle parameters including the carbon footprint and water footprint would be necessary to validate this claim. Overall, the study highlights the potential of utilizing perlite-based modifiers to enhance the thermal insulation of geopolymers while addressing environmental concerns.
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Carbohydr Polym
March 2025
Shanghai Key Laboratory of Regulatory Biology, School of Life Sciences, East China Normal University, Shanghai 200241, PR China. Electronic address:
Cellulose foams are renewable and biodegradable materials that are promising substitutes for plastic foams. However, the scale-up fabrication of cellulose foams is severely hindered by technological complexity and cost- and time-consuming drying processes. Here, we developed a facile and robust method to fabricate cellulose foams via oven-drying following surfactant-assisted mechanical foaming of cellulose nanofibers (CNFs).
View Article and Find Full Text PDFSmall
January 2025
School of Mechanical Engineering, Korea University, 145 Anam-Ro, Seongbuk-Gu, Seoul, 02841, Republic of Korea.
Passive temperature controls like passive daytime radiative cooling (PDRC)-heating (PDRH), and thermal insulation are essential to meet the growing demand for energy-efficient thermal solutions. When combined with advanced functions like electromagnetic interference shielding, these technologies can significantly enhance scalability. However, existing approaches using single thin films or uniform porous materials face inherent limitations in optimizing versatile functions, while lightweight, insulating aerogels can extend their multifunctionality by manipulating pores and fillers.
View Article and Find Full Text PDFNano Lett
January 2025
Guangdong Basic Research Center of Excellence for Structure and Fundamental Interactions of Matter, Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, School of Physics, South China Normal University, Guangzhou 510006, China.
Coulomb attraction with weak screening can trigger spontaneous exciton formation and condensation, resulting in a strongly correlated many-body ground state, namely, the excitonic insulator. One-dimensional (1D) materials natively have ineffective dielectric screening. For the first time, we demonstrate the excitonic instability of single atomic wires of transition metal telluride MTe (M = Mo, W), a family of 1D van der Waals (vdW) materials accessible in the laboratory.
View Article and Find Full Text PDFSensors (Basel)
December 2024
Department of Electromechanical Engineering, University of Beira Interior, Rua Marquês d'Ávila e Bolama, 6201-001 Covilhã, Portugal.
This article presents the development of a resistive frost-detection sensor fabricated using Fused Filament Fabrication (FFF) with a conductive filament. This sensor was designed to enhance demand-defrost control in industrial refrigeration systems. Frost accumulation on evaporator surfaces blocks airflow and creates a thermal insulating barrier that reduces heat exchange efficiency, increasing energy consumption and operational costs.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Nano Science and Nano Engineering Department, Ataturk University, Erzurum 25240, Turkey.
The main purpose of this study is to prepare a melamine aniline formaldehyde foam, an MAF copolymer, with lower water sensitivity and non-flammability properties obtained by the condensation reaction of melamine, aniline, and formaldehyde. In addition, the preparation of MAFF composites with organoclay reinforcement was determined as a secondary target in order to obtain better mechanical strength, heat, and sound insulation properties. For the synthesis of foams, the microwave irradiation technique, which offers advantages such as faster reactions, high yields and purities, and reduced curing times, was used together with the heating technique and the effect of organoclay content on the structural and textural properties of foams and both heat insulation and mechanical stability was investigated.
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