Conversion of Oil-Containing Residue from Waste Oil Recycling Plant into Porous Carbon Materials Through Activation Method with Phosphoric Acid.

In the waste oil recycling industry, large amounts of oil-containing sludge are still generated, thus posing a resource depletion issue when disposed of or incinerated without energy recovery or residual oil utilization. In this work, chemical activation experiments using phosphoric acid (HPO) were performed at a low temperature (600 °C) for 30 min to produce porous carbon products. From the results of the pore property analysis, an increasing trend with an increasing impregnation ratio from 0.5 to 2.0 was observed. Based on the Brunauer-Emmett-Teller (BET) model, the maximal BET surface area was about 70 m/g, which was indicative of the hysteresis loop and the type IV isotherms in the resulting carbon product. In addition, the enhancement in the pore properties of the carbon products obtained through acid-washing was superior to that achieved through water-washing and without post-washing. From observations made using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS), the carbon products featured a porous structure and inherent magnetism due to their richness of iron oxides. In this regard, they can be used as efficient adsorbents or catalyst supports due to their simple recovery (or separation) when exhausted.