This paper analyzes the behavior of the entropy of a nuclear fuel rod under deep burnup conditions, beyond standard operational ranges, reaching up to 60 years. The evolution of the neutron source distribution in a pressurized water reactor (PWR) fuel pin was analyzed using the Monte Carlo method and Shannon information entropy. To maintain proper statistics, a novel scaling method was developed, adjusting the neutron population based on the fission rate. By integrating reactor physics with information theory, this work aimed at the deeper understanding of nuclear fuel behavior under extreme burnup conditions. The results show a "U-shaped" entropy evolution: an initial decrease due to self-organization, followed by stabilization and eventual increase due to degradation. A minimum entropy state is reached after approximately 45 years of pin operation, showing a steady-state condition with no entropy change. This point may indicate a physical limit for fuel utilization. Beyond this point, entropy rises, reflecting system degradation and lower energy efficiency. The results show that entropy analysis can provide valuable insights into fuel behavior and operational limits. The proposed scaling method may also serve to control a Monte Carlo simulation, especially for the analysis of long-life reactors.
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http://dx.doi.org/10.3390/e26121124 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Institute of Physical Chemistry, RWTH Aachen University, Landoltweg 2, 52074 Aachen, Germany.
We combine atomistic and continuum simulation methods to study the defect chemistry of a model grain boundary in UO. Using atomistic methods, we calculate the formation energies of oxygen interstitials, uranium vacancies, and hole polarons (U ions) across the Σ5(310)[001] symmetric tilt grain boundary. This information is then used as input in a continuum model of point-defect concentrations at the grain boundary and in its vicinity, taking into account electrostatic (space-charge) effects.
View Article and Find Full Text PDFPol J Radiol
December 2024
Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, Tehran, Iran.
Purpose: This study explored the use of computer-aided diagnosis (CAD) systems to enhance mammography image quality and identify potentially suspicious areas, because mammography is the primary method for breast cancer screening. The primary aim was to find the best combination of preprocessing algorithms to enable more precise classification and interpretation of mammography images because the selected preprocessing algorithms significantly impact the effectiveness of later classification and segmentation processes.
Material And Methods: The study utilised the mini-MIAS database of mammography images and examined the impact of applying various preprocessing method combinations to differentiate between malignant and benign breast lesions.
Appl Radiat Isot
January 2025
Department of Physics, K. N. Toosi University of Technology, P.O. Box 16315-1618, Tehran, Iran.
Safe storage of fresh and irradiated fuel is ensured by solving the problem of photon emission protection. The neutron component is usually not taken into account due to its low intensity. However, for the new VVER-1200 fuel, the neutron component consideration is a mandatory procedure for radiation safety.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Petroleum Engineering, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran.
Purpose: Biodiesel is a non-toxic, renewable, and environmentally friendly fuel used in compression ignition engines. This work aimed to develop FeO/SiO as a cheap, magnetic, and easy separable catalyst for biodiesel production from waste oil by sono-catalytic transesterification.
Methods: Fe₃O₄-SiO₂ was prepared using a modified Stober method and used as a heterogeneous catalyst in an ultrasound-assisted transesterification reaction to produce biodiesel.
Acc Chem Res
January 2025
Department of Chemistry, University at Buffalo, State University of New York, Buffalo, New York 14260, United States.
ConspectusUnderstanding f element-ligand covalency is at the center of efforts to design new separations schemes for spent nuclear fuel, and is therefore of signficant fundamental and practical importance. Considerable effort has been invested into quantifying covalency in f element-ligand bonding. Over the past decade, numerous studies have employed a variety of techniques to study covalency, including XANES, EPR, and optical spectroscopies, as well as X-ray crystallography.
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