The physical process in the macroscopic world unfolds along a single time direction, while the evolution of a quantum system is reversible in principle. How to recover a quantum system to its past state is a complex issue of both fundamental and practical interests. In this article, we experimentally demonstrate a novel method for recovering the state in quantum walks (QWs), also known as full-state revival. Moreover, we observe two other important phenomena in QWs, recurrence and periodicity, via simplifying and repeatedly implementing the scheme, respectively. Our experiments show that obtaining these phenomena requires neither any information of the initial state nor full information of the coin operations. Our work sheds new light on quantum state engineering and recovery, and the initialization of quantum devices based on QWs.
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http://dx.doi.org/10.1093/nsr/nwae263 | DOI Listing |
Polymers (Basel)
December 2024
Department of Physics, Moscow State University, 119991 Moscow, Russia.
The effective use of polymer carbon dots (PCD) in various fields of science and technology requires a more detailed understanding of the mechanisms of their photoluminescence formation and change as a result of their interaction with the environment. In this study, PCD synthesized via a hydrothermal method from citric acid and ethylenediamine are studied in various solvents using FTIR spectroscopy, optical absorption spectroscopy, and photoluminescence spectroscopy. As a result of the analysis of the obtained dependencies of such PCD spectral characteristics as the photoluminescence FWHM, the photoluminescence quantum yield, the photoluminescence lifetime on the acidity and basicity of the solvent, a hypothesis was formulated on the formation mechanism of hydrogen bonds between the PCD surface groups and the molecules of the environment, and conclusions were made about the donor-acceptor nature of the synthesized PCD.
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December 2024
Department of Chemistry, Faculty of Environment, Life, Natural Sciences and Technology, Okayama University, Okayama 700-8530, Japan.
Thanks to recent developments in spectrophotometric instruments, the spectra, quantum yields (Φ), and lifetimes () of photoluminescence from organic and inorganic compounds can be readily determined not only in solution but also in the solid state. It is known that naphthalene emits fluorescence in solution, but not in the solid state. In a previous paper, we reported that solid-state emission can be seen from biaryl compounds comprised of chromophores that show no emission in the solid state.
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December 2024
State Key Laboratory of Molecular Engineering of Polymers, Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200438, China.
With the development and improvement of analysis and detection systems, low-toxicity and harmless detection systems have received much attention, especially in the field of food detection. In this paper, a low-toxicity dual-emission molecularly imprinted fluorescence sensor (CdTe QDs@SiO/N-CDs@MIPs) was successfully designed for highly selective recognition and visual detection of tetracycline (TC) in food samples. Specifically, the non-toxic blue-emission N-doped carbon dots (N-CDs) with high luminous performance acted as the response signals to contact TC via the covalent bond between amino and carboxyl groups.
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December 2024
School of Chemistry and Chemical Engineering, School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China.
Sphalerite flotation is generally achieved by copper activation followed by xanthate collection. This study aims to propose a design idea to find novel collectors from the perspective of molecular design and prove the theoretical feasibility that the collector can effectively recover sphalerite without copper activation. To address this, 30 compounds containing different structures of sulfur atoms and different neighboring atoms were designed based on coordination chemistry.
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December 2024
Department of Chemistry & Biochemistry, University of Mississippi, University, MS 38677, USA.
Molecular dyes containing carbazole-based π bridges and/or julolidine-based donors should be promising molecules for intense SWIR emission with potential application to molecular bioimaging. This study stochastically analyzes the combinations of more than 250 organic dyes constructed within the D-π-D (or equivalently D-B-D) motif. These dyes are built from 22 donors (D) and 14 π bridges (B) and are computationally examined using density functional theory (DFT).
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