This study investigated the potential of substituting wheat flour with drum-dried overripe Kepok plantain flour (KPF) to enhance instant the nutritional and textural properties of noodles. Noodles were prepared with varying KPF substitutions (10%, 20%, and 30%) and compared to a control (0% KPF). The results show that KPF remarkably influences the adhesiveness, springiness, cohesiveness, and hardness of noodles. Notably, 10% KPF substitution yielded noodles with moderate elasticity and good shape retention but increased their firmness. Increasing the KPF substitution resulted in less sticky noodles, with noodles with 20% KPF substitution showing improved elasticity and shape retention but a firmer texture. At 30% substitution, noodles were less sticky and slightly softer, although their shape retention somewhat decreased. Moreover, KPF substitution greatly altered the pasting properties of flour. Increasing the KPF substitution resulted in lower peak viscosity values, indicating a potential for stronger gelling of amylose in the noodles. This modification aligns with the desired characteristics of alkaline noodles, suggesting that KPF substitution, particularly at 30%, can improve the gelling properties and overall quality of the final product. Furthermore, KPF substitution improved the cooking quality, resulting in shorter cooking times and lower cooking losses than control noodles. This is attributed to the lower water uptake of KPF noodles, leading to a slimmer shape after cooking. Furthermore, KPF substitution increased the content of resistant starch and decreased oil absorption during frying. This study highlights the potential of KPF as a functional ingredient for developing more nutritious and sustainable instant noodles.
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http://dx.doi.org/10.3746/pnf.2024.29.4.554 | DOI Listing |
Prev Nutr Food Sci
December 2024
Research Center for Agroindustry, National Research and Innovation Agency, KST Soekarno, Cibinong 16911, Indonesia.
Dalton Trans
August 2024
Department of Chemistry, Indian Institute of Technology, Kharagpur, 721 302, Kharagpur, India.
In this study, the reaction between 2-(3,5-dimethylpyrazolylmethyl)-5-(dimethylaminomethyl)pyrrole and thiophenol under heating conditions afforded the new ligand 2-(3,5-dimethylpyrazolylmethyl)-5-(phenylthiomethyl)pyrrole 2. The reaction of 2 with -chloroperbenzoic acid provided sulfoxide 3 and sulfone 4 group-containing ligands. The reaction of 2 with copper(I) halides provided the binuclear complexes [Cu(μ-X){μ-CHN-2-(CHMepz)-5-(CHSPh)-κ-S,N}] (X = Cl, Br and I, 5-7) in high yields.
View Article and Find Full Text PDFInorg Chem
May 2024
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Building 4, Moscow 119071, Russia.
The redox state of the phthalocyanine in sandwich lanthanide complexes is crucial for their applications. In this work, we demonstrate that the cation-induced supramolecular assembly of crown-substituted phthalocyanine lanthanide complexes Ln[(15C5)Pc] can be used to control the redox state of the ligand simultaneously with the coordination sphere of the central metal. We achieve unprecedented redox switching of phthalocyanine ligands in a double-decker Gd(III) complex, resulting from the intramolecular inclusion of potassium cations between the decks with simultaneous twisting of the ligands (the skew angle between them decreases from 44.
View Article and Find Full Text PDFDalton Trans
December 2018
Université de Strasbourg, Université de Haute-Alsace, CNRS, LIMA, UMR 7042, Ecole européenne de Chimie, Polymères et Matériaux, 25 rue Becquerel, 67087 Strasbourg, France. and Institut Universitaire de France, 75000 Paris, France.
Neutral nickel-N-heterocyclic carbene complexes, (κ-C)-[NiCpBr{R-NHC-(CH)SR'}] [Cp = η-CH; R-NHC-(CH)SR' = 1-mesityl-3-[2-(tert-butylthio)ethyl]- (1a), 1-mesityl-3-[2-(phenylthio)ethyl]- (1b), 1-benzyl-3-[2-(tert-butylthio)ethyl]- (1c), 1-benzyl-3-[2-(phenylthio)ethyl]-imidazol-2-ylidene (1d)], which bear a N-bound thioether side arm, were prepared by the reaction of nickelocene with the corresponding imidazolium bromides [R-NHC-(CH)SR'·HBr] (a-d), via conventional or microwave heating. The H NMR spectra of the benzyl-substituted species 1c and 1d showed signals for diastereotopic NCHCHS protons at room temperature. However, structural studies established the absence of coordination of the sulphur atom in the solid state, and solvent DFT calculations showed that bromide displacement by sulphur is an unfavourable process (ΔG = +13.
View Article and Find Full Text PDFChemistry
November 2017
Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.
[2.2]Paracyclophane, with its unique structure, allows the design of unusual 3D structures by functionalization of this rigid and stable hydrocarbon scaffold. Therefore different mono- and homodisubstituted [2.
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