Severity: Warning
Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 176
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3122
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
Elemental analysis, infrared spectroscopy, and X-ray single crystal diffraction indicated that a novel metal-organic framework (Tb-MOF) designated as 0.5n[Hbpy]·[Tb(dpa)(HO)]·4nHO was synthesized successfully, (where Hdpa = 5-(3, 4-dicarboxy- phenoxy) isophenic acid, bpy = protonated 4,4'-bipyridine). Tb-MOF adopts a 3D network structure based on Tb ions and the (dpa) ligand through µ: η, η, η, η binding modes. Various luminescent EuTb-MOFs were prepared by adjusting Tb and Eu concentrations. Fluorescence analysis revealed Tb-MOF's strong fluorescence and excellent sensing ability for pollutants like nitrobenzene (NB), ornidazole (ORN), and fluridine (Flu) in water. It is worth noting that the fluorescence quenching rate of Tb-MOF for nitrobenzene can reach 97.1 %, which is also one of the highest among Ln-MOFs. XPS, LUMO orbital energy levels, fluorescence lifetime, and UV absorption were employed to explore the fluorescence quenching mechanism. Tb-MOF demonstrates robust anti-counterfeiting properties and stability, particularly against Flu, and allows rapid in situ imaging of pesticide residues on vegetables. Moreover, leveraging the adjustable emission spectra of EuTb-MOF, a barcode system for anti-counterfeiting labels has been developed, showing the versatility of stable metal-organic frameworks in advanced technologies for anti-counterfeiting applications.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.saa.2024.125669 | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!