A solvent-controlled unprecedented tandem reaction of readily accessible SeO, a wide variety of sulfonyl hydrazides, and alkynes has been established for the chemodivergent construction of structurally complex 1,2-bis(()-1-aryl-2-arylsulfonylvinyl)diselanes and bis(()-1-aryl-2-(arylsulfonyl)vinyl)selanes via a catalyst-free one-pot three-component approach, respectively. The adjustable and controlled synthetic strategy shows good yields and chemoselectivities for most substrates under mild and simple conditions.
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Solvent-Controlled Cascade Reaction of SeO, Sulfonyl Hydrazides and Alkynes for Chemoselective Access to Symmetric Divinyl Sulfones Substituted Seleniums and Diseleniums.
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College of Chemistry and Chemical Engineering, Taiyuan University of Technology, 79 West Yingze Street, Taiyuan 030024, People's Republic of China.
A solvent-controlled unprecedented tandem reaction of readily accessible SeO, a wide variety of sulfonyl hydrazides, and alkynes has been established for the chemodivergent construction of structurally complex 1,2-bis(()-1-aryl-2-arylsulfonylvinyl)diselanes and bis(()-1-aryl-2-(arylsulfonyl)vinyl)selanes via a catalyst-free one-pot three-component approach, respectively. The adjustable and controlled synthetic strategy shows good yields and chemoselectivities for most substrates under mild and simple conditions.
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