AI Article Synopsis
- The study examines how the surface properties and electrical conductivity of betaine-based ionic liquids change when mixed with different concentrations of gabapentin at a specific temperature.
- The findings show that as gabapentin concentration and the length of the alkyl chain increase, surface tension decreases, indicating stronger interactions.
- Additionally, micellization parameters improve with longer chains, while conductivity decreases at higher gabapentin concentrations due to increased viscosity and ion interactions.
Article Abstract
This study investigates the surface properties, micellization, and electrical conductivity of betaine-based ionic liquids (ILs) composed of [R-bet][Br] where R represents the C, C and C (specifically [Cbet][Br], [Cbet][Br], and [Cbet][Br]) in aqueous gabapentin solutions at concentrations of (0.0000, 0.0100, 0.0300, and 0.0500) mol kg at 298.15 K. The surface tension measurements revealed that increasing gabapentin concentration and alkyl chain length decrease surface tension, indicating significant hydrophobic and hydrophilic interactions. The related thermophysical micellization parameters, including critical micelle concentration (CMC) and minimum surface area per molecule (A), exhibited improved micellization and interfacial efficiency with longer alkyl chains. Thermodynamic analysis confirm the spontaneous nature of micelle formation, with more negative Gibbs free energy values for SAILs with longer alkyl chains. The electrical conductivity studies indicate lower limiting molar conductivity (Λ) at higher gabapentin concentrations, due to increased viscosity and ion-ion interactions. Ion association constants (K) and DFT-COSMO calculations support stronger hydrophobic interactions and molecular packing influenced by alkyl chain length and gabapentin.
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|---|---|
| http://dx.doi.org/10.1038/s41598-024-83777-7 | DOI Listing |
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11695968 | PMC |
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