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Discipline of Dietetics, Department of Nursing and Allied Health, School of Health Sciences, Swinburne University of Technology, SPW203, Swinburne Place West Building, 1 John St, Hawthorn, VIC, 3122, Australia.

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In contrast to the traditional perspective that thermal fluctuations are insignificant in surface dynamics, here we report their influence on surface reaction dynamics. Using real-time low-energy electron microscopy imaging of NiAl(100) under both vacuum and O atmospheres, we demonstrate that transient temperature variations substantially alter the direction of atom diffusion between the surface and bulk, leading to markedly different oxidation outcomes. During heating, substantial outward diffusion of atoms from the bulk to the surface results in step growth.

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Clinical Manifestations.

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