Herein, the reduction of the Cu oxidation state during the CO electro-reduction reaction (CORR) is effectively inhibited by depositing C supramolecular clusters onto the Cu(OH)F surface. By utilizing the unique electronic buffering capacity of C, a significant number of Cu/Cu sites are created, leading to a remarkable faradaic efficiency of C products up to 76.9% and exceptional stability.
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| http://dx.doi.org/10.1039/d4cc03987d | DOI Listing |
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