Severity: Warning
Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 176
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3122
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
The heterojunction materials are considered as promising electrocatalyst candidates that empower advanced lithium-sulfur (Li-S) batteries. However, the detailed functional mechanism of heterojunction materials to boost the sulfur redox reaction kinetics remains unclear. Herein, we construct a multifunctional potential well-type Bi2Te3/TiO2 topological insulator (TI) heterojunction with electric dipole domain to elucidate the synergistic mechanism, which facilitates rapid mass transport, strengthens polysulfide capture ability and accelerates polysulfide conversion. Therefore, the Li-S battery with Bi2Te3/TiO2 TI heterojunction modified separator achieves high utilization of sulfur cathode, delivering a high reversible specific capacity of 1375 mAh g-1 at 0.2 C and long cycling capability with a negligible capacity decay of 0.022% per cycle over 1000 cycles at 1 C. Even with the high sulfur loading of 13.2 mg cm-2 and low E/S ratio of 3.8 µL mg-1, a high area capacity of 11.2 mAh cm-2 and acceptable cycling stability can be obtained. This work provides guidance for designing high-efficiency TI heterojunctions to promote the practical application of Li-S batteries.
Download full-text PDF |
Source |
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http://dx.doi.org/10.1002/anie.202423357 | DOI Listing |
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