Immobilization or mobilization of heavy metal(loid)s in lake sediment-water interface: Roles of coupled transformation between iron (oxyhydr)oxides and natural organic matter.

Iron (Fe) (oxyhydr)oxides and natural organic matter (NOM) are active substances ubiquitously found in sediments. Their coupled transformation plays a crucial role in the fate and release risk of heavy metal(loid)s (HMs) in lake sediments. Therefore, it is essential to systematically obtain relevant knowledge to elucidate their potential mechanism, and whether HMs provide immobilization or mobilization effect in this ternary system. In this review, we summarized (1) the bidirectional effect between Fe (oxyhydr)oxides and NOM, including preservation, decomposition, electron transfer, adsorption, reactive oxygen species production, and crystal transformation; (2) the potential roles of coupled transformation between Fe and NOM in the environmental behavior of HMs from kinetic and thermodynamic processes; (3) the primary factors affecting the remediation of sediments HMs; (4) the challenges and future development of sediment HM control based on the coupled effect between Fe and NOM from theoretical and practical perspectives. Overall, this review focused on the biogeochemical coupling cycle of Fe, NOM, and HMs, with the goal of providing guidance for HMs contamination and risk control in lake sediment.