In the field of gun launched missile extended range rocket, the propellant grain in the rocket needs to withstand significant launch loads during their firing phase, and also bear the high pressure caused by ignition, and the impact of launch overloads and ignition shocks on the structural integrity of propellants becomes very important. So this work investigated the dynamic initiation fracture toughness of the composite modified double-base (CMDB) propellant by both experiments and numerical simulations. The dynamic mechanical properties test of the cracked straight through flattened Brazilian disc (CSTFBD) specimens were conducted using a modified Split Hopkinson pressure bar (SHPB). By comparing the results of quasi static and dynamic numerical simulations, it was found that dynamic fracture initiation toughness can be determined by time-to-fracture using the quasi-static theory. The numerical simulation results combined with the ZWT constitutive model agree well with the experimental results, indicating that ZWT constitutive model is suitable for numerical simulation calculation of propellant structural integrity under dynamic load, and provides a theoretical basis for propellant structural integrity analysis under dynamic load. During the measurement of the mechanical response, the fracture surfaces of the dynamic test specimens were observed by electron microscopy scanning. Then the evolution of the microstructure synchronously was obtained. The scanning electron microscope (SEM) results revealed that fracture modes and breakage of the ammonium perchlorate (AP) particles in the surface layer played an important role in determining the failure mechanism, which revealed the failure mechanism of the propellant under dynamic load. The result of experimental measurement showed the influence of loading rate on the dynamic fracture initiation toughness of CMDB propellant.
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http://dx.doi.org/10.1038/s41598-024-83854-x | DOI Listing |
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11686013 | PMC |
Sci Rep
December 2024
School of Mechanical Engineering, Key Laboratory of Special Engine Technology, Ministry of Education, Nanjing University of Science and Technology, Nanjing, 210094, People's Republic of China.
In the field of gun launched missile extended range rocket, the propellant grain in the rocket needs to withstand significant launch loads during their firing phase, and also bear the high pressure caused by ignition, and the impact of launch overloads and ignition shocks on the structural integrity of propellants becomes very important. So this work investigated the dynamic initiation fracture toughness of the composite modified double-base (CMDB) propellant by both experiments and numerical simulations. The dynamic mechanical properties test of the cracked straight through flattened Brazilian disc (CSTFBD) specimens were conducted using a modified Split Hopkinson pressure bar (SHPB).
View Article and Find Full Text PDFRSC Adv
August 2023
School of Chemical Engineering, Northwest University Xi'an Shaanxi 710069 China
Metal organic complexes are regarded as a series of promising combustion catalysts for solid rocket propellants. Their effects on the combustion performance of propellants are closely related to the reaction mechanism. Here, the metal-organic complex Cu(Salen) was investigated as a candidate material for the combustion catalyst of the HMX-added composite modified double-base propellant (HMX-CMDB).
View Article and Find Full Text PDFJ Mol Model
November 2022
Shijiazhuang Campus, Army Engineering University of PLA, Shijiazhuang, 050003, China.
ReaxFF molecular dynamics (ReaxFF MD) simulations were performed to study the thermal decomposition property of cyclotrimethylenetrinitramine (RDX)-based composite modified double base (CMDB) propellants. The intermediate products and final products of the decomposition of RDX-based CMDB propellants at 2000 K, 2500 K, and 3000 K are obtained. The simulation results show that the decomposition of RDX and RDX/HTPB/Al is primary triggered by N-NO rupture, and then, the intermedia products undergo a series of complex interactions to form final products.
View Article and Find Full Text PDFNanomaterials (Basel)
October 2021
The Third Department, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China.
The effects of different types of nano-sized metal particles, such as aluminum (nAl), zirconium (nZr), titanium (nTi), and nickel (nNi), on the properties of a variety of solid rocket propellants (composite, fuel-rich, and composite modified double base (CMDB)) were analyzed and compared with those of propellants loaded with micro-sized Al (mAl) powder. Emphasis was placed on the investigation of burning rate, pressure exponent (), and hazardous properties, which control whether a propellant can be adopted in solid rocket motors. It was found that nano-sized additives can affect the combustion behavior and increase the burning rate of propellants.
View Article and Find Full Text PDFJ Hazard Mater
July 2017
Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4, Kosygina Str., 119991 Moscow, Russia; Novosibirsk State University, 2, Pirogova Str., 630090 Novosibirsk, Russia; Institute of Chemical Kinetics and Combustion, 3, Institutskaya Str., 630090 Novosibirsk, Russia.
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