Severity: Warning
Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 144
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 144
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 212
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 1002
Function: getPubMedXML
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3142
Function: GetPubMedArticleOutput_2016
File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
The present work investigated the application of UVC combined with electrogenerated HO (UVC/e-HO) for BTA degradation using a Printex L6 carbon-based (PL6C) gas diffusion electrode (GDE). The studies were carried out by analyzing the influence of the current density, pH and initial BTA concentration in the contaminant degradation process. Under optimal conditions using 0.05 mol L KSO as supporting electrolyte, BTA removal was evaluated in different water matrices. In all cases, 100% of BTA elimination was reached in the first 15 minutes of treatment under the UVC/e-HO process, while mineralization rates ranging between 59.2 and 78.0% were obtained after 90 minutes of electrolysis. The active species O and e played an important role in the BTA removal. The toxicity test conducted on the river water sample post-treatment using the Lactuca sativa L seeds showed that the BTA by-products had low toxicity. The results obtained from the LC-ESI-MS/MS analyses showed the same BTA degradation by-products when the BTA-containing water matrices were treated using the UVC/e-HO and photo-electro-Fenton processes. The PL6C-GDE developed in the study exhibited high efficiency when applied for HO electrogeneration and BTA degradation. Additionally, the electrode demonstrated remarkable stability and durability, enabling the generation of reproducible data for up to 81h of continuous operation.
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Source |
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http://dx.doi.org/10.1016/j.chemosphere.2024.144016 | DOI Listing |
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