Highly porous, self-supported 3D interconnected network-based nanomaterials hold immense promise in revolutionizing the field of catalysis. These materials combine two critical features; a large accessible surface and an overall active surface that leads to substantial catalytic effects. In this study, we developed a novel class of 3D composite material composed of zinc oxide tetrapods (ZOT) and polyethylene glycol (PEG) polymer, specifically designed for photocatalysis. A polymer composite of ZOT with PEG has been synthesized with 2.5 wt.% ZOT powder mixed with a PEG solution forming a 3D electrode. A consistent composite solution was obtained using probe-sonication and its thick layers were deposited on various substrates using the spin coating technique which were subsequently characterized for optical, morphological, and structural properties. The catalytic response of the fabricated 3D composite was evaluated both in solution and thin film forms under UV exposure. The surface-engineered ZOT-PEG composites showed an excellent capability to degrade the methylene blue (MB) dye in different forms under UV and normal light, opening their potential scopes in environmental remediation.
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http://dx.doi.org/10.1038/s41598-024-68840-7 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, College of Environmental Science and Engineering, Hunan University, Changsha 410082, China.
Electrocatalytic dehalogenation is a promising method for the remediation of chlorinated organic pollutants. The dehalogenation performance is controlled by catalytic activity, and the underlying electrocatalytic dehalogenation mechanisms need to be carefully investigated for guiding the design of catalyst. Here we report the preparation of a new Pd-based catalyst with a nanosheet structure (Pd NS) by a simple wet-chemical reduction method.
View Article and Find Full Text PDFSensors (Basel)
January 2025
School of Computing, Mathematics and Engineering, Charles Sturt University, Bathurst, NSW 2795, Australia.
Soil colour is a key indicator of soil health and the associated properties. In agriculture, soil colour provides farmers and advises with a visual guide to interpret soil functions and performance. Munsell colour charts have been used to determine soil colour for many years, but the process is fallible, as it depends on the user's perception.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Co-Innovation Center for Sustainable Forestry in Southern China, College of Life Sciences, Nanjing Forestry University, Nanjing 210037, China.
The prerequisite for breeding a plant to be used in phytoremediation is its high tolerance to grow normally in soil contaminated by certain heavy metals. As mechanisms of plant uptake and transport of nickel (Ni) are not fully understood, it is of significance to utilize exogenous genes for improving plant Ni tolerance. In this study, from encoding an exporter of Ni and cobalt was overexpressed constitutively in , and the performance of transgenic plants was assayed under Ni stress.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Joint International Research Laboratory of Information Display and Visualization, School of Electronic Science and Engineering, Southeast University, Nanjing 210096, China.
This study presents a facile one-pot synthesis method to fabricate BiFeO-BiFeO-BiO heterojunction photocatalysts with controllable compositions and pure phases. Three different binary heterojunctions (BiFeO/BiFeO, BiFeO/BiO, and BiFeO/BiO) and a ternary BiFeO/BiFeO/BiO heterojunction were formed, all exhibiting significantly enhanced photocatalytic performance for the degradation of methylene blue (MB) and phenol under visible light irradiation, outperforming the individual compositions. Notably, the BiFeO/BiFeO heterojunction achieved the highest degradation efficiency (93.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Department of Microbiology, Faculty of Pharmaceutical Sciences, Medical University of Silesia, Jagiellońska 4, 41-200 Sosnowiec, Poland.
The presented study investigated the possibility of using the MC5 strain, isolated from raw sewage by the enrichment culture method, in the bioremediation of soil contaminated with selected NSAIDs, i.e., ibuprofen (IBF), diclofenac (DCF), and naproxen (NPX), using the bioaugmentation technique.
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