Porous Organic Polymers for CO Capture and Catalytic Conversion.

Overuse of fossil fuels and anthropogenic activities have led to excessive emissions of carbon dioxide, leading to global warming, and measures to reduce atmospheric carbon dioxide concentrations are needed to overcome this global challenge. Therefore, exploring an environmentally friendly strategy for capturing airborne CO and converting it into high-value-added chemicals offers a promising pathway toward "carbon neutrality". In recent years, porous organic polymers have attracted much attention for carbon capture and the catalytic conversion of carbon dioxide because of their high specific surface area, high chemical stability, nanoscale porosity, and structural versatility, which make them easy to functionalize. In this review, we introduce the preparation methods for various POPs, the types of POPs adsorbed during carbon dioxide capture, and the progress in the use of POPs for the photocatalytic and chemicatalytic conversion of carbon dioxide, with a special discussion on the influence of adsorption type on the efficiency of catalytic conversion. Finally, we propose a prospective direction for the subsequent development of this field.