AI Article Synopsis
- The flexibility of 2,2'-bipyridyl-based diamine and coordination domain denticity allowed for the creation of four different structures stabilized by silver-silver pairs.
- Reactions with 2,6-diformylpyridine produced silver(I)-stabilized molecular tweezer, trefoil knot, and Solomon link.
- The 1,8-naphthyridine-based dialdehyde led to the formation of [2]catenanes and trefoil knot, with notable close distances between silver ions and two assemblies exhibiting interesting luminescent properties.
Article Abstract
A subtle interplay between the flexibility of the 2,2'-bipyridyl-based diamine and the denticity of the coordination domain formed upon self-assembly enabled the formation of four distinct topologies stabilised by [Ag⋅⋅⋅Ag] pairs. The reactions utilising 2,6-diformylpyridine resulted in the formation of silver(I)-stabilised molecular tweezer, trefoil knot, and Solomon link. The 1,8-naphthyridine-based dialdehyde promoted the formation of [2]catenanes and trefoil knot, demonstrating very close Ag⋅⋅⋅Ag distances. Two of the studied assemblies demonstrated interesting luminescent properties in the solid state.
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| http://dx.doi.org/10.1002/anie.202423962 | DOI Listing |
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