Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 143
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 994
Function: getPubMedXML
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3134
Function: GetPubMedArticleOutput_2016
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
As a unique property of the interlocked structures, rotaxane allows for intramolecular motions between its wheel and axle components. Introduction of rotaxanes into polymers can endow them with distinctive macroscopic features and outstanding mechanical properties. Here, we prepare a copillar[5]arene with a hydroxyl and an amino-group on each end, which can spontaneously form a pseudo[1]rotaxane through intramolecular hydrogen bonds. This pseudo[1]rotaxane possesses a releasable extra alkyl chain, which is then incorporated into a linear polyurethane by reacting with a diisocyanate to prepare polyurethane elastomers with spring-like structures. The results of stress-strain test and dynamic mechanical analysis all indicate that sliding motions of the axle part on the pseudo[1]rotaxane in the polymer skeleton can greatly dissipate energy, which endows the elastomers with higher toughness and better fatigue resistance. Moreover, the addition of moderate amount of cuprous bromide to form cuprous-thioether coordination in the polymers can further improve the mechanical properties.
Download full-text PDF |
Source |
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http://dx.doi.org/10.1002/anie.202421557 | DOI Listing |
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