Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 143
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3098
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
Severity: Warning
Message: Attempt to read property "Count" on bool
Filename: helpers/my_audit_helper.php
Line Number: 3100
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3100
Function: _error_handler
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
The gas-liquid-solid interface plays a crucial role in various electrochemical energy conversion devices, including fuel cells and electrolyzers. Understanding the effect of gas transfer on the electrochemistry at this three-phase interface is a grand challenge. Scanning electrochemical cell microscopy (SECCM) is an emerging technique for mapping the heterogeneity in electrochemical activity; it also inherently features a three-phase boundary at the nanodroplet cell. Herein, we quantitatively analyze the role of the three-phase boundary in SECCM involving gas via finite element simulation. Oxygen reduction reaction is used as an example for reaction with a gas reactant, which shows that interfacial gas transfer can enhance the overall mass transport of reactant, allowing measuring current density of several A/cm. The hydrogen evolution reaction is used as an example for reaction with a gas product, and fast interfacial gas transfer kinetics can significantly reduce the concentration of dissolved gas near the electrode. This helps to measure electrode kinetics at a high current density without the complication of gas bubble formation. The contribution of interfacial gas transfer can be understood by directly comparing its kinetics to the mass transfer coefficient from the solution. Our findings aid the quantitative application of SECCM in studying electrochemical reactions involving gases, establishing a basis for investigating electrochemistry at the three-phase boundary.
Download full-text PDF |
Source |
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11659987 | PMC |
http://dx.doi.org/10.1021/acsmeasuresciau.4c00061 | DOI Listing |
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