Methyl 2-[()-5-methyl-2-oxoindolin-3-yl-idene]hydrazinecarbodi-thio-ate.

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EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, United Kingdom.

Published: October 2024

The title di-thio-carbazate imine, CHNOS, was obtained from the condensation reaction of -methyl-dithio-carbazate (SMDTC) and 5-methyl-isatin. It shows a configuration about the imine C=N bond, which is associated with an intra-molecular N-H⋯O hydrogen bond that closes an (6) ring. In the crystal, inversion dimers linked by pairwise N-H⋯O hydrogen bonds generate (8) loops. The extended structure features C-H⋯S contacts as well as reciprocal carbon-yl-carbonyl (C=O⋯C=O) inter-actions.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11660172PMC
http://dx.doi.org/10.1107/S2414314624009672DOI Listing

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