AI Article Synopsis
- - The crystal growth of 2-(3,4,5-triphenylphenyl)acetic acid from acetonitrile produces a monosolvate (CHO·CHCN) that belongs to space group 1.
- - The molecule features a unique conformation where three phenyl rings are arranged like a paddlewheel around a central benzene ring, with the carboxyl group positioned nearly perpendicular to this ring.
- - The crystal structure consists of inversion-symmetric dimer units connected by hydrogen bonds and further linked through C-H⋯O=C interactions, creating one-dimensional aggregates aligned along the [111] axis, with additional weak interactions involving acetonitrile.
Article Abstract
Crystal growth of 2-(3,4,5-triphen-ylphen-yl)acetic acid () from aceto-nitrile yields a monosolvate, CHO·CHCN, of the space group 1. In the crystal, the title mol-ecule adopts a conformation in which the three phenyl rings are arranged in a paddlewheel-like fashion around the central arene ring and the carboxyl residue is oriented nearly perpendicular to the plane of this benzene ring. Inversion-symmetric dimers of O-H⋯O-bonded mol-ecules of represent the basic supra-molecular entities of the crystal structure. These dimeric mol-ecular units are further linked by C-H⋯O=C bonds to form one-dimensional supra-molecular aggregates running along the crystallographic [111] direction. Weak C-H⋯N inter-actions occur between the mol-ecules of and aceto-nitrile.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11660473 | PMC |
| http://dx.doi.org/10.1107/S2056989024009976 | DOI Listing |
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