Halong Bay (northern Vietnam) is heavily affected by human activities. Metals and metalloids (e.g., Al, Cu, Hg, Ni, Sb, Pb, V; MM) were used as proxies to assess the origin and transport of anthropogenic inputs. The chronology of inputs was examined according to different particle transport pathways using two sediment cores, one from coastal waters (HL) exposed to both atmospheric deposition and the Red River drainage, and the other from a small isolated lake on an islet (HT) receiving only atmospheric deposition. Higher accumulation rates were observed in HL (0.449 g cm year) than in HT (0.069 g cm year). In both cores, all anthropogenic MM fluxes are controlled by sedimentation processes regardless of their origin and transport pathways. Results show that coastal waters are strongly influenced by Red River drainage with specific events recorded in 1947 (Indochina War), 1960 (first five-year plan), 1974 and 1985 (flash flooding) and 2002 (Tuyen Quang Dam landslides). In HL core, the highest variabilities were observed for Cr, Hg, Ni, Pb and V with surface maxima of 67.7, 0.107, 26.0, 31.4, 82.2 μg g, respectively. Geochemical ratios (Pb/Hg and V/Ni) showed specific signatures related to fossil fuel combustion. Estimated Pb deposition fluxes follow the increase in CO emissions in the region.
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http://dx.doi.org/10.1016/j.marpolbul.2024.117490 | DOI Listing |
Anal Chim Acta
January 2025
College of Resources and Environment, Southwest University, Chongqing, 400716, China; Key Laboratory of Biomedical Analytics (Southwest University), Chongqing Science and Technology Bureau, College of Pharmaceutical Sciences, Southwest University, Chongqing, 400715, China. Electronic address:
Background: Because arsenate (As(V)) is a highly toxic pollutant, timely on-site monitoring of its concentration is crucial for mitigating potential environmental and health hazards. Traditional on-site detection methods for As(V) often face limitations of long response time and low sensitivity. Nanozymes are nanomaterials that exhibit enzyme-like catalytic activity.
View Article and Find Full Text PDFChemosphere
January 2025
Laboratory of Zoology, Research Institute for Biosciences, University of Mons, Mons, Belgium. Electronic address:
Recently, there has been growing concern about the impacts of metal pollutants on insect populations, particularly as human societies increasingly rely on metal-based technologies. Unlike organic pollutants, metals - both essential and non-essential - are non-degradable and readily accumulate in insect tissues, sometimes reaching hazardous levels. While numerous studies address how insects cope with pesticide pollution, there is a notable scarcity of knowledge regarding their abilities to confront metal pollution.
View Article and Find Full Text PDFEcotoxicol Environ Saf
January 2025
Department of Biosystems and Technology, Swedish University of Agricultural Sciences, Alnarp 23456, Sweden. Electronic address:
Nickel (Ni) is required in trace amounts (less than 500 µg kg) in plants to regulate metabolic processes, the immune system, and to act as an enzymatic catalytic cofactor. Conversely, when nickel is present in high concentration, it is considered as a toxic substance. Excessive human nickel exposure occurs through ingestion, inhalation, and skin contact, ultimately leading to respiratory, cardiovascular, and chronic kidney diseases.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Departamento de Química Orgánica y Bio-Orgánica, Universidad Nacional de Educación a Distancia (UNED), Avenida de Esparta s/n, Las Rozas de Madrid 28232, Spain. Electronic address:
Magnetite nanoparticles have been successfully used for removal and immobilization of contaminants in water, yet their application in soils combined with in situ magnetic separation remains unexplored. We evaluated the effectiveness and optimal conditions for using magnetite nanoparticles combined with magnetic separation to remove metal(loid)s from contaminated mine soils. Soil samples were incubated (15, 45 days) with varying doses of magnetite (0, 25, 50 g kg⁻¹) and moisture (dry, field capacity) and separated using electromagnet or permanent magnet.
View Article and Find Full Text PDFSci Total Environ
January 2025
Institute of Plant Nutrition, Resources and Environment, Beijing Academy of Agriculture and Forestry Sciences, Beijing 100097, China. Electronic address:
Composting urban and rural wastes into organic fertilizers for land application is considered the best way to dispose of and recycle waste resources. However, there are some concerns about the long-term effects of applying various organic fertilizers on soils, food safety, and health risks derived from heavy metal(loid)s (HMs). A long-term field experiment was conducted to evaluate the effects of continuous application of chicken manure compost (CM), sewage sludge compost (SSC), and domestic waste compost (DWC) for wheat on the accumulation, transfer, and health risks of HMs.
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