Historical trends of metals and metalloids into lake and coastal sediments of Halong Bay (Vietnam).

Mar Pollut Bull

Aix Marseille University, Université de Toulon, CNRS, IRD, MIO UM110, 13288 Marseille, France; Department Water-Environment-Oceanography, University of Science and Technology of Hanoi (USTH), Vietnamese Academy of Science and Technology (VAST), 18 Hoang Quoc Viet, Hanoi 100000, Viet Nam; IRD, Chulalongkorn University, 254 Henri Dunant Road, Pathumwan, 10330 Bangkok, Thailand.

Published: December 2024

AI Article Synopsis

  • Halong Bay in northern Vietnam is experiencing significant environmental impact from human activities, specifically from metals and metalloids used as indicators for tracing anthropogenic contributions.
  • Two sediment cores, one from coastal waters and another from a small isolated lake, revealed that the coastal site (HL) had a much higher accumulation rate than the lake site (HT).
  • Key findings indicate that the coastal waters are heavily influenced by the Red River drainage, with particular historical pollution spikes linked to significant events like the Indochina War and various regional flooding incidents.

Article Abstract

Halong Bay (northern Vietnam) is heavily affected by human activities. Metals and metalloids (e.g., Al, Cu, Hg, Ni, Sb, Pb, V; MM) were used as proxies to assess the origin and transport of anthropogenic inputs. The chronology of inputs was examined according to different particle transport pathways using two sediment cores, one from coastal waters (HL) exposed to both atmospheric deposition and the Red River drainage, and the other from a small isolated lake on an islet (HT) receiving only atmospheric deposition. Higher accumulation rates were observed in HL (0.449 g cm year) than in HT (0.069 g cm year). In both cores, all anthropogenic MM fluxes are controlled by sedimentation processes regardless of their origin and transport pathways. Results show that coastal waters are strongly influenced by Red River drainage with specific events recorded in 1947 (Indochina War), 1960 (first five-year plan), 1974 and 1985 (flash flooding) and 2002 (Tuyen Quang Dam landslides). In HL core, the highest variabilities were observed for Cr, Hg, Ni, Pb and V with surface maxima of 67.7, 0.107, 26.0, 31.4, 82.2 μg g, respectively. Geochemical ratios (Pb/Hg and V/Ni) showed specific signatures related to fossil fuel combustion. Estimated Pb deposition fluxes follow the increase in CO emissions in the region.

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http://dx.doi.org/10.1016/j.marpolbul.2024.117490DOI Listing

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