In this study, an inorganic multilayer barrier film was fabricated on the polyethylene naphthalate (PEN) substrate, which was composed of a SiO layer prepared by inductively coupled plasma chemical vapor deposition (ICP-CVD) and a AlO/ZnO nanolaminate produced by plasma-enhanced atomic layer deposition (PEALD). The multilayer composite film with a structure of 50 nm SiO + (4.5 nm AlO/6 nm ZnO) × 4 has excellent optical transmittance (88.1%) and extremely low water vapor permeability (3.3 × 10 g/m/day, 38 °C, 90% RH), indicating the cooperation of the two advanced film growth methods. The results suggest that the defects of the SiO layer prepared by ICP-CVD were effectively repaired by the PEALD layer, which has excellent defect coverage. And AlO/ZnO nanolaminates have advantages over single-layer AlO due to their complex diffusion pathways. The multilayer barrier film offers potential for encapsulating organic electronic devices that require a longer lifespan.
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http://dx.doi.org/10.3390/ma17236007 | DOI Listing |
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11643419 | PMC |
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