Influence of Recycling and UV Exposure on the Properties of 3D Printing Polymer Materials.

The use of polymer materials in various fields has increased significantly due to their ease of thermoforming and relatively low production costs. The production volume of these materials is extremely high, and according to forecasts from global statistical centers, it is expected to continue rising in the future. However, the extensive use and easy availability of polymeric materials have caused significant ecological problems. The world faces large amounts of polymer waste and environmental pollution. Plastic recycling remains challenging due to issues related to sorting polymer waste and separating it according to polymer types. Recycling certain plastics requires only a quarter of the energy needed to produce new plastic. To address this, circular economy principles should be applied to 3D printing products made from polymeric materials. A particularly wide application of these technologies is found when polymeric materials are used due to their low cost, low melting temperatures, and other advantageous properties. This paper investigates the impact of plastic recycling on the quality of 3D-printed products. During the research, samples were 3D printed and tested using both virgin and recycled PLA, ABS, and PET-G materials. The samples underwent static and dynamic tests to determine their mechanical properties, such as tensile strength, elongation, and impact resistance. The research results showed that the properties of recycled polymer materials deteriorate, with relative elongation of recycled and 3D-printed materials decreased by 16-45%. Despite this, recycled polymer materials can still be used, but it is necessary to account for the reduction in plasticity when creating products that will be exposed to dynamic loads. The impact strength is reduced by 6% for PLA, 54% for ABS, and 58% for PET-G. Additionally, the research included tests on samples printed with 3D printing technology that were exposed to UV irradiation. The results indicated similar dependences, as UV exposure also affects the reduction of material plasticity. After 66 Wh/m of UV radiation, the tensile strength of PET-G and PLA decreased by 17%, while ABS showed a reduction of about 5%.