Illuminating for purity: Photocatalytic and photothermal membranes for sustainable oil-water separation.

The integration of photocatalytic and photothermal materials with oil-water separation membranes marks a significant advancement in sustainable separation technologies. These hybrid membranes exhibit exceptional functionalities, including resistance to oil fouling, self-cleaning, antibacterial properties, and reduced oil viscosity. Based on their reaction mechanisms, current photocatalytic and photothermal membranes are categorized into four types, i.e., photocatalytic membranes, photo-Fenton membranes, PMS-assisted photocatalytic membranes, and photothermal membranes. Under light irradiation, photocatalytically functionalized membranes generate reactive oxygen species (ROS) that degrade organic pollutants and inactivate bacteria on the membrane surfaces, enabling in-situ cleaning and regeneration. In addition to the above benefits, photothermal membranes achieve reduction of oil viscosity for higher membrane permeation and removal of light oil from membrane surfaces through light-induced heating. This review first explores the mechanisms underlying light-driven advanced oxidation processes (AOPs) and photothermal effects, followed by an in-depth discussion on the fabrication methods of these membranes. Additionally, the applications of photocatalytic and photothermal membranes in oil-water separation are examined, with an emphasis on how the photocatalytic and photothermal materials contribute to membrane functionality. Finally, this review presents the challenges currently faced by photocatalytic and photothermal membranes and outlines future research directions.