We have developed an effective one-step extrusion method to prepare a nodeless chalcogenide hollow-core anti-resonance fiber, characterized by excellent symmetry and less requirements for drawing pressure in achieving the desired wall thickness. The resulting fiber exhibits excellent uniformity, with an ultra-large effective mode area of 21970 µm and a low overlap factor of = 0.03%. It can withstand an input power exceeding 10 W at 4.5 µm and maintain a stable output power of 1.2 W at an input power of 5.25 W, all while preserving a high beam quality with an M value of 1.09. The output single-mode laser remains highly stable when the translation offset of the laser coupling into the fiber is less than 100 µm. The chalcogenide hollow-core fibers with watt-level mid-infrared laser delivery power and near-diffraction-limited beam quality can be used for practical applications in industry, medicine, and defense.
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http://dx.doi.org/10.1364/OL.541805 | DOI Listing |
Appl Spectrosc
December 2024
Zentrum für Rieskrater und Impaktforschung, Nördlingen, Germany.
In situ optical analytical spectroscopies offer great geochemical insights due to their capability to resolve the chemical composition of regolith surfaces of rocky celestial bodies. The use of suitable calibration targets improves the precision of mineral determination, which is of critical importance for short-living, low-mobility landers, and enables, in special cases, determination of elemental composition. We investigate the capabilities of three space-relevant optical analytical techniques used for in situ mineralogical analysis, i.
View Article and Find Full Text PDFSmall
December 2024
Research Center for Crystal Materials, State Key Laboratory of Functional Materials and Devices for Special Environmental Conditions, Xinjiang Key Laboratory of Functional Crystal Materials, Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi, 830011, China.
Infrared nonlinear optical (NLO) crystal materials exert a crucial role in laser technology, which is extensively utilized in the fields of medical laser, long-distance laser communication, infrared laser guidance, etc. Currently, the commercially available infrared NLO crystals are diamond-like structural crystals AgGaQ (Q = S, Se) and ZnGeP. However, their applications are significantly limited owing to their inherent drawbacks, such as low laser damage thresholds and narrow band gaps.
View Article and Find Full Text PDFEnviron Sci Technol
December 2024
Institute of Earth Surface Dynamics, University of Lausanne, Lausanne 1015 CH, Switzerland.
Interactions among microbes, minerals, and organic matter are key controls on carbon, nutrient, and contaminant dynamics in soils and sediments. However, probing these interactions at relevant scales and through time remains an analytical challenge due to both their complex nature and the need for tools permitting nondestructive and real-time analysis at sufficient spatial resolution. Here, we demonstrate the ability and provide analytical recommendations for the submicron-scale characterization of complex mineral-organic microstructures using optical photothermal infrared (O-PTIR) microscopy.
View Article and Find Full Text PDFAppl Spectrosc
December 2024
Research Division of Environmental Analytics, Process Analytics and Sensors, Institute of Chemical Technologies and Analytics, TU Wien, Vienna, Austria.
Volatile organic compounds (VOCs) are an ever-growing hazard for health and environment due to their increased emissions and accumulation in the air. Quantum cascade laser-based infrared (QCL-IR) sensors hold significant promise for gas monitoring, thanks to their compact, rugged design, high laser intensity, and high molecule-specific detection capabilities within the mid-infrared spectrum's fingerprint region. In this work, tunable external cavity QCLs were complemented by an innovative germanium-on-silicon integrated optics waveguide sensing platform with integrated microlenses for efficient backside optical interfacing for the tunable laser spectrometer.
View Article and Find Full Text PDFAppl Spectrosc
December 2024
Department of Electrical and Photonics Engineering, Technical University of Denmark, Kongens Lyngby, Denmark.
Combining near-infrared (NIR) and mid-infrared (MIR) spectroscopy to cover both the fundamental and overtone combination molecular vibrational resonances allows more robust analytical methods to be used, such as two-dimensional correlation spectroscopy. However, due to the strong differences in molar absorption coefficients and transparency of the optical material, it is inherently difficult to perform NIR and MIR spectroscopy on aqueous samples using a single instrument. Combining spectra from different instruments and sample presentations can result in unwanted spectral variations, which can influence the prediction models and mitigate the advantages of the combination approaches.
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