AI Article Synopsis
- The study uses -tartaric acid to modify the chirality of dynamic aggregates formed by a perylenebisimide dye with boronic acid groups.
- A notable transition in the circular dichroism (CD) effect is observed, shifting from an S-shaped to an anti-S-shaped pattern when L-/D-tartaric acid is introduced.
- Structural changes in the chiral aggregates are linked to the influence of -tartaric acid, indicating its role in tuning aggregate properties.
Article Abstract
We report the use of the -isomer of tartaric acid, -tartaric acid, to tune the chirality of the dynamic aggregates of a perylenebisimide dye bearing boronic acid groups in the presence of enantiomeric L-/D-tartaric acid. The CD-ee dependence changes from S- to anti-S-shaped. A change in the structures of the chiral aggregates led by the -tartaric acid is identified.
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| http://dx.doi.org/10.1039/d4cc05345a | DOI Listing |
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