The development of anode materials with high rate performance as well as favourable working durability is key for next-generation lithium-ion batteries (LIBs). Here, MgVO is reported as an advanced anode material, using a facile and scalable solution combustion technology. The MgVO anode shows a "near-zero" volume change (<10% over 1000 cycles). This can be explained by a solid-solution Li storage mechanism, leading to superior cycling stability. Consequently, the MgVO electrode achieves a remarkable capacity of approximately 102.6 mA h g at 2.0 A g, along with a low fading rate of 0.001% per cycle over 3000 cycles.
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http://dx.doi.org/10.1039/d4cc05716c | DOI Listing |
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