The efficient mitigation of harmful nitrogen oxides (NO) under ambient conditions remains a challenging task. Selective adsorption offers a viable solution for the capture of low-concentration NO from the polluted stream at low temperatures. This review summarizes recent progress in the development of NO adsorbents, delves into the understanding of adsorption mechanisms, and discusses the criteria for evaluating their performance. First, the present NO adsorbents are categorized according to their distinct characteristics. This review then provides insights into the mechanisms of adsorption, highlighting the interaction between active sites and NO, drawing from both experimental and theoretical research. The performance of these adsorbents is also assessed, focusing on their capacity, reusability, stability and selectivity. Finally, perspectives are proposed to address the significant challenges and explore potential advancements for NO adsorbents, aiming to enhance their suitability for diverse practical application scenarios.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1002/adma.202401623 | DOI Listing |
Sci Rep
January 2025
College of Mechanical Engineering, Zhejiang University of Technology, No.18, Chaowang Road, Hangzhou, 310014, Zhejiang Province, China.
To observe the chemical mechanical polishing (CMP) process at the atomic scale, reactive force field molecular dynamics (ReaxFF-MD) was employed to simulate the polishing of 6 H-SiC under three conditions: dry, pure water, and HO solution. This study examined the reactants on the surface of 6 H-SiC during the reaction in the HO solution, along with the dissociation and adsorption processes of HO and water molecules. The mechanisms for atom removal during the CMP process were elucidated.
View Article and Find Full Text PDFTalanta
December 2024
Department of Food Science and Engineering, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China; Shenzhen Key Laboratory of Food Macromolecules Science and Processing, Shenzhen University, Shenzhen 518060, China. Electronic address:
The simultaneous detection and removal of Ag from drinking water was crucial for preventing human health, while it was also extremely challenging due to bifunctional materials that combine both Ag adsorption and detection functions rarely being explored. In this study, a benzotrithiophene-based covalent organic framework (TAPA-BTT) was synthesized and applied to detect and remove Ag. TAPA-BTT exhibited high crystallinity, a large specific surface area, and good thermal stability.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Key Laboratory of Chem-Biosensing of Anhui Province, Key Laboratory of Functional Molecular Solids of Anhui Province, College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, Anhui, China. Electronic address:
Adsorption and biodegradation are two important means to remove the pollutants from the environment, but how to combine them and improve the catalytic performance and stability of free enzyme are facing great challenges. Herein, lipase from Candida rugosa (CRL) was immobilized into bimetallic ZnCo-MOF by biomineralization, which not only significantly improved the catalytic activity and stability of CRL but also endowed it with excellent reusability. Furthermore, CRL@ZnCo-MOF established a synergetic system of combined adsorption and enzymatic degradation for the sustainable removal of dibutyl phthalate (DBP) in actual water environment.
View Article and Find Full Text PDFSci Total Environ
January 2025
Department of Earth Resources and Environmental Engineering, Hanyang University, Seoul 04763, Republic of Korea. Electronic address:
The CO adsorption capacity of biochar depends on the type of biomass used and its physicochemical properties; various sorption parameters including temperature, CO concentration, and humidity affect the CO adsorption capacity. Biochar derived from defatted black soldier fly larvae (BSFL) biomass was investigated for direct CO capture and exhibited a hydrophilic/mesoporous structure that contained high concentrations of alkali and alkaline metals (>10 wt%), which contribute to CO chemisorption. The CO adsorption efficiency was higher at 25 °C compared with that at 30 °C and 35 °C, probably due to reduced Brownian motion of CO molecules at lower temperatures.
View Article and Find Full Text PDFJ Chromatogr B Analyt Technol Biomed Life Sci
December 2024
Hunan Provincial Key Laboratory of Anti-Resistance Microbial Drugs, Department of Pharmacy, The Third Hospital of Changsha, Changsha 410015, People's Republic of China. Electronic address:
Individualized medication with peptide antibiotics, guided by therapeutic drug monitoring, is essential to treat infections caused by multidrug-resistant bacteria. Peptide antibiotics exhibit an "on-off" elution mechanism on a C18 column, leading to adsorption at the column inlet in all-aqueous conditions. Unlike small molecules, column length minimally influences their retention, with longer columns simply broadening peptide antibiotic peaks due to unnecessary post-column volume.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!