Small bodies are capable of delivering essential prerequisites for the development of life, such as volatiles and organics, to the terrestrial planets. For example, empirical evidence suggests that water was delivered to the Earth by hydrated planetesimals from distant regions of the Solar System. Recently, several morphologically inactive near-Earth objects were reported to experience significant nongravitational accelerations inconsistent with radiation-based effects, and possibly explained by volatile-driven outgassing. However, these "dark comets" display no evidence of comae in archival images, which are the defining feature of cometary activity. Here, we report detections of nongravitational accelerations on seven additional objects classified as inactive (doubling the population) that could also be explainable by asymmetric mass loss. A detailed search of archival survey and targeted data rendered no detection of dust activity in any of these objects in individual or stacked images. We calculate dust production limits of [Formula: see text]10, [Formula: see text], and [Formula: see text] kg s[Formula: see text] for 1998 FR[Formula: see text], 2001 ME[Formula: see text], and 2003 RM with these data, indicating little or no dust surrounding the objects during the observations. This set of dark comets reveals the delineation between two distinct populations: larger, "outer" dark comets on eccentric orbits that are end members of a continuum in activity level of comets, and smaller, "inner" dark comets on near-circular orbits that could signify a different different population. These objects may trace various stages in the life cycle of a previously undetected, but potentially numerous, volatile-rich population that may have provided essential material to the Earth.
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Proc Natl Acad Sci U S A
December 2024
Institute for Astronomy, University of Hawaii, Honolulu, HI 96822.
Small bodies are capable of delivering essential prerequisites for the development of life, such as volatiles and organics, to the terrestrial planets. For example, empirical evidence suggests that water was delivered to the Earth by hydrated planetesimals from distant regions of the Solar System. Recently, several morphologically inactive near-Earth objects were reported to experience significant nongravitational accelerations inconsistent with radiation-based effects, and possibly explained by volatile-driven outgassing.
View Article and Find Full Text PDFACS Appl Mater Interfaces
April 2024
Advanced Porous Materials Unit, IMDEA Energy Institute, Avda. Ramón de la Sagra, 3, Móstoles 28935, Madrid, Spain.
The need to develop green and cost-effective industrial catalytic processes has led to growing interest in preparing more robust, efficient, and selective heterogeneous catalysts at a large scale. In this regard, microwave-assisted synthesis is a fast method for fabricating heterogeneous catalysts (including metal oxides, zeolites, metal-organic frameworks, and supported metal nanoparticles) with enhanced catalytic properties, enabling synthesis scale-up. Herein, the synthesis of nanosized UiO-66-NH was optimized via a microwave-assisted hydrothermal method to obtain defective matrices essential for the stabilization of metal nanoparticles, promoting catalytically active sites for hydrogenation reactions (760 kg·m·day space time yield, STY).
View Article and Find Full Text PDFACS Earth Space Chem
January 2024
Department of Physics & Astronomy, Wellesley College, Wellesley, Massachusetts 02481, United States.
We demonstrate for the first time that Galactic cosmic rays with energies as high as ∼10 eV can trigger a cascade of low-energy (<20 eV) secondary electrons that could be a significant contributor to the interstellar synthesis of prebiotic molecules whose delivery by comets, meteorites, and interplanetary dust particles may have kick-started life on Earth. For the energetic processing of interstellar ice mantles inside dark, dense molecular clouds, we explore the relative importance of low-energy (<20 eV) secondary electrons-agents of radiation chemistry-and low-energy (<10 eV), nonionizing photons-instigators of photochemistry. Our calculations indicate fluxes of ∼10 electrons cm s for low-energy secondary electrons produced within interstellar ices due to attenuated Galactic cosmic-ray protons.
View Article and Find Full Text PDFJ Clin Epidemiol
December 2023
Division of Immunology, Immunity to Infection and Respiratory Medicine, School of Biological Sciences, The University of Manchester, Manchester, UK; North West Lung Centre, Wythenshawe Hospital, Manchester University NHS Foundation Trust, Manchester Academic Health Science Centre, Manchester, UK; Acute Intensive Care Unit, Wythenshawe Hospital, Manchester University NHS Foundation Trust, Manchester Academic Health Science Centre, Manchester, UK.
Objectives: To inform clinical practice guidelines, randomized controlled trials (RCTs) of the management of pneumonia need to address the outcomes that are most important to patients and health professionals using consistent instruments, to enable results to be compared, contrasted, and combined as appropriate. This systematic review describes the outcomes reported in clinical trials of pneumonia management and the instruments used to measure these outcomes.
Study Design And Setting: Based on a prospective protocol, we searched MEDLINE/PubMed, Cochrane CENTRAL and clinical trial registries for ongoing or completed clinical trials evaluating pneumonia management in adults in any clinical setting.
J Appl Toxicol
March 2024
F.M. Kirby Neurobiology Center, Boston Children's Hospital, Boston, Massachusetts, USA.
Agriculture commonly utilizes crop protection products to tackle infestations from fungi, parasites, insects, and weeds. Validamycin A, an inhibitor of trehalase, possesses antibiotic and antifungal attributes. Epidemiological evidence has led to concerns regarding a potential link between pesticide usage and neurodegenerative diseases.
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