In the title compound, di-phenyl-tin(IV) diiso-thio-cyanate, [Sn(NCS)(CH)] or PhSn(NCS), comparatively long tin-nitro-gen and short tin-sulfur bonds prove that the ambidentate iso-thio-cyanate ion acts as a bridge between two neighboring, octa-hedrally coordinated tin atoms. As a result, the mol-ecules lose their individuality in favor of a layered coordination polymer that represents a new type of mol-ecular inter-actions in the structural chemistry of diorganotin(IV) dihalides/pseudohalides. The tin atom is located on a center of inversion.
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| http://dx.doi.org/10.1107/S2414314624010939 | DOI Listing |
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