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Tri-phenyl-phospho-nium tri-chlorido-(tri-phenyl-phosphane-κ)cobaltate(II) benzene disolvate. | LitMetric

Tri-phenyl-phospho-nium tri-chlorido-(tri-phenyl-phosphane-κ)cobaltate(II) benzene disolvate.

IUCrdata

Nelson Mandela University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth, 6031, South Africa.

Published: November 2024

AI Article Synopsis

Article Abstract

The solvated title compound, (CHP)[CoCl(CHP)]·2CH, is the tri-phenyl-phospho-nium salt of an anionic Co chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent mol-ecules shows rotational disorder. C-H⋯Cl and P-H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618865PMC
http://dx.doi.org/10.1107/S2414314624011210DOI Listing

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Tri-phenyl-phospho-nium tri-chlorido-(tri-phenyl-phosphane-κ)cobaltate(II) benzene disolvate.

IUCrdata

November 2024

Nelson Mandela University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth, 6031, South Africa.

The solvated title compound, (CHP)[CoCl(CHP)]·2CH, is the tri-phenyl-phospho-nium salt of an anionic Co chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent mol-ecules shows rotational disorder. C-H⋯Cl and P-H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].

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