This study examined the effects of the alkaline Maillard reaction on the structural, interfacial, and functional properties of soybean 11S globulin-debranched starch (DBS) conjugates. The results showed that the degree of DBS binding to 11S globulin was influenced by the polymer ratios, which in turn affected the structural, interfacial, and functional characteristics. The 11S-DBS conjugates with a 2:1 biopolymer ratio exhibited the highest grafting degree, largest zeta potential absolute value, smallest particle size, and greatest thermal stability. Conjugates with higher globulin content demonstrated superior interfacial and functional properties, including improved solubility, increased surface hydrophobicity, and reduced interfacial tension. 3D fluorescence scanning revealed a decrease in the signal of aromatic amino acid residues, while microstructural observation provided insights into the binding behavior of different 11S-DBS conjugates. Molecular docking simulations highlighted the key role of hydrogen bonding in the formation of these conjugates. This study enhances understanding of soybean globulin-polysaccharide interaction mechanisms, expanding their potential applications in the food, medical, and bioengineering industries.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.carbpol.2024.123054 | DOI Listing |
Nat Commun
December 2024
College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, Nanjing University, Nanjing, China.
Early disease diagnosis hinges on the sensitive detection of signaling molecules. Among these, hydrogen sulfide (HS) has emerged as a critical player in cardiovascular and nervous system signaling. On-chip immunoassays, particularly nanoarray-based interfacial detection, offer promising avenues for ultra-sensitive analysis due to their confined reaction volumes and precise signal localization.
View Article and Find Full Text PDFNat Commun
December 2024
Key Laboratory of Materials Chemistry for Energy Conversion and Storage of Ministry of Education (HUST), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST), Wuhan, 430074, China.
Large-amount encapsulation and subsequent expressing are common characteristics for many biomedical applications, such as cosmetic creams and medical ointments. Emulsion gels can accomplish that, but often undergo exclusive, complex, multiple synthesis steps, showing extremely laborious and non-universal. The method here is simple via precisely interfacial engineering in homogenizing a nanoparticle aqueous dispersion and a polymer oil solution, gaining interfacial 45° three-phase-contact-angle for the nanoparticle that can bridge across oil emulsions' interfaces and ultimately form interconnected macroscopic networks.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry, Jilin Provincial International Joint Research Center of Photo-functional Materials and Chemistry, Changchun 130022, China; State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun 130021, China. Electronic address:
The power conversion efficiency (PCE) of ternary all-small-molecule organic solar cells (T-ASM-OSCs) differs significantly from that of the polymer systems (2 %), and the role of third component remains unclear. The electron donor of coumarin derivatives with simple structure and strong and broad light absorption has high PCE for T-ASM-OSCs composed of non-fullerene acceptors (Y6 and DBTBT-IC). Here, we calculated the electronic structure and interfacial properties of the binary C1-CN:Y6 and ternary C1-CN:Y6:DBTBT-IC systems using molecular dynamic (MD) simulations and density functional theory (DFT) to explore the role of the third component (DBTBT-IC).
View Article and Find Full Text PDFFundam Res
November 2024
School of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, China.
Electronic packaging is an essential branch of electronic engineering that aims to protect electronic, microelectronic, and nanoelectronic systems from environmental conditions. The design of electronic packaging is highly complex and requires the consideration of multi-physics phenomena, such as thermal transport, electromagnetic fields, and mechanical stress. This review presents a comprehensive overview of the multiphysics coupling of electric, magnetic, thermal, mechanical, and fluid fields, which are crucial for assessing the performance and reliability of electronic devices.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300400 PR China. Electronic address:
The formation and growth of lithium dendrites is an ever-present and urgent problem in lithium-ion batteries (LIBs). At the same time, the low melting point of commercial polyolefin separators may lead to safety issues during application. On this basis, in this work, poly (m-phenylene isophthalamide) (PMIA)/Zr-based metal-organic framework (NH-UiO-66) composite separator was prepared by non-solvent induced phase separation (NIPS).
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!