New insights into extracellular polymeric substance degradation during dewaterability of sludge by UV-driven advanced reduction processes: Role of hydrated electron and spectroscopic profiling of dissolved organic components in sludge filtrate.

Currently, Advanced Reduction Process (ARP) is gaining popularity as an alternative to Advanced Oxidation Process (AOP). Though UV/Sulfite process is effective in degrading organic compounds, no investigation has been done using ARP to improve sludge dewaterability. Here, effect of two different ARP's (UV/Sulfite; UV/Sulfide) that generates hydrated electron (e) and hydrogen atom (H•) in enhancing sludge dewatering was explored. Based on findings, alkaline pH was favourable for ARP's to improve sludge dewatering. At optimal conditions, CST value was 18 and 23.3 s for UV/Sulfite and UV/Sulfide with raw sludge exhibiting 100 s at pH-7.7 respectively. The mechanism revealed that e was the dominant reducing radical along with H•, based on EPR spectra and quenching experiments. UV-Vis, Gaussian fitting, 3D EEM Fluorescence and Synchronous Fluorescence Spectroscopy exhibited higher release of organic matter and aromaticity which agrees with FTIR analysis. Emission peak around 330-380 nm in all samples exhibited Microbial Soluble Products and aromatic protein II.