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Interlayer Ions Control Spin Canting in Low-Dimensional Manganese Trimers in 12R-BaMnO ( = Ce, Pr) Layered Perovskites. | LitMetric

AI Article Synopsis

Article Abstract

To synthetically target a specific material with select performance, the underlying relationship between structure and function must be understood. For targeting magnetic properties, such understanding is underdeveloped for a relatively new class of layered hexagonal perovskites, the 12R-BaMnO family. Here, we perform a detailed magnetostructural study of the layered hexagonal perovskite materials 12R-BaMnO, where = diamagnetic Ce or paramagnetic ≈ 1/2 Pr. The material with = Ce is an antiferromagnet below ≈ 7.75 K, while the material with = Pr exhibits more complex behavior, with a net moment below 200 K and a sharp peak in the susceptibility at ≈ 12.15 K. Guided by the susceptibility data, we conduct variable-temperature powder neutron diffraction measurements to determine the magnetic structure of these two materials. The introduction of a magnetic interlayer cation cants the spins in the MnO trimers out of plane. We further characterize the crystal and electronic structures in these compounds using powder X-ray diffraction and X-ray absorption spectroscopy measurements coupled with first-principles theoretical calculations. The resulting detailed picture of the magnetic, crystal, and electronic structure will be useful for understanding the magnetism in similar 12R hexagonal perovskites and related materials.

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http://dx.doi.org/10.1021/acs.inorgchem.4c03915DOI Listing

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