The complex composition of solid waste leads to the variability of flue gas emissions during its incineration, which poses a challenge to the stable operation of incineration and pollution control systems. To address this problem, the study explored a new method to predict the concentrations of flue gas pollutants during incineration based on the composition of mixed solid waste using machine learning. Through comprehensive model interpretation and analysis, the important influence of waste composition characteristics on the generation of flue gas pollutants during incineration was deeply explored. The study found that rubber and plastic components significantly promoted the conversion of C to CO during waste incineration; N content and C/N ratio had a significant effect on the generation of NO; S content and C/S ratio affected the generation of SO; Cl content and C/Cl ratio had a significant effect on the generation of HCl, especially with PVC components. The extreme gradient boosting tree (XGBOOST) model optimized by feature engineering showed more excellent R-validation (0.98, 0.94, 1.00, 0.98, 1.00, 0.98) for predicting CO, CO, NO, NO, SO, and HCl concentration, than K-nearest neighbor (KNN), random forest (RF), and light gradient boosting machine (LGBM). This study provides a new prediction and optimization method for waste incineration plants, which can guide the regulation of feedstock and incineration parameters, thus improving operating efficiency and pollution control. It is of great significance to promote sustainable waste management and environmental protection.
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http://dx.doi.org/10.1016/j.jenvman.2024.123588 | DOI Listing |
J Colloid Interface Sci
December 2024
College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, PR China. Electronic address:
NH-MIL-125 with abundant porosity and specific interactions with CO molecules, has been demonstrate great potential in the field of photocatalytic CO reduction. However, conventional NH-MIL-125 and their composites much lower CO photoreduction efficiency in aerobic environments because of the O competition. To circumvent the issue, this study modifies NH-MIL-125 through crystal facet engineering to enhance its selective CO adsorption and photocatalytic efficiency in the environment of impurity CO.
View Article and Find Full Text PDFJ Environ Manage
December 2024
College of Environmental and Municipal Engineering, Qingdao University of Technology, Qingdao, 266520, China.
The disposal of municipal solid waste (MSW) is a significant source of greenhouse gas (GHG) emissions. As incineration becomes the primary method of MSW disposal in China, MSW incineration (MSWI) plants are expected to play a crucial role in mitigating GHG emissions in the waste sector. This study estimated the quarterly GHG emissions from two representative MSWI plants in Qingdao using a life-cycle assessment (LCA) approach.
View Article and Find Full Text PDFHuan Jing Ke Xue
January 2025
Shaanxi Key Laboratory of Environmental Engineering, School of Environment and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China.
Domestic waste treatment is an important source of anthropogenic greenhouse gas emissions, and it is of great significance to clarify the carbon emission intensity of each link before and after waste classification treatment to help with the "double carbon" goal. Based on the relevant data on domestic waste generation in Baoji City in 2021, combined with the integrated urban and rural domestic waste disposal model, the carbon emission intensity of urban and rural domestic waste treatment before and after classification was calculated using the IPCC inventory guide carbon emission factor method. The results showed that by reducing the proportion of simple landfills in rural areas, the carbon reduction could reach 59 451.
View Article and Find Full Text PDFChemistry
December 2024
Guangdong Pharmaceutical University, Guangzhou Higher Education Mega Center, 510006, Guangzhou, CHINA.
Among the various studies on CO2 utilization, the sustainable and cost-effective fixation of CO2 into cyclic carbonates remains one of the most intriguing subjects. To this end, a novel type of composite dicationic ionic liquid material, DIL@PDIL, was developed. This composite consists of a dicationic ionic liquid (DIL), DMAP[TMGH]Br, supported on a polymeric dicationic ionic liquid (PDIL), P-DVB/Im[TMGH]Br.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Ruhr University Bochum, Analytische Chemie, Universitätsstr 150, 44780, Bochum, GERMANY.
The direct CO2 reduction reaction (CO2RR) from simulated flue gas of various CO2 concentrations could minimize extra energy for pre-concentration processes to highly concentrated CO2 as a feed-stock. We investigate the challenges for CO2RR caused by low CO2 concentrations and provide strategies concerning the impact of the chosen electrocatalyst material and the selection of the electrolyte to attain high CO selectivity. We continuously feed CO2 mixed with N2 (the typical dilutant in flue gas) in various ratios to gas diffusion electrodes in a model flow-through electrolyzer.
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