Self-Similar Ligand for 2D Zr(IV)-Based Metal-Organic Frameworks: Fluorescent Sensing and Catalysis.

Two-dimensional (2D) metal-organic framework sheets, in comparison to the 3D analogues, offer potential advantages for intercalation of guest components between the layers, exfoliation/dispersion into solutions, and processing into thin films. As a versatile platform for leveraging organic functions, the 2D Zr(IV)-carboxylate net here features a dendritic Sierpinski tritopic linker with conjugated alkyne branches and a photoactive triphenylamine core. The 2D solid can be easily dispersed in water and many other solvents, resulting in stable and fluorescent suspension for sensing nitro aromatic compounds and Fe ions with high quenching efficiencies and ultralow limits of detection. Also, the neighboring alkyne units of the coordination solid undergo thermal cyclization (e.g., at 320 °C) to form cross-linked nanographene-like components to afford robust porosity, which substantially takes up PdCl (atomic ratio of Zr/Pd, 2.4:1) to afford a heterogeneous catalyst for Suzuki-Miyaura coupling reactions─direct in air and without the need for phosphine ligands.