AI Article Synopsis
- The study introduces a new approach to improve organic macrocyclic hosts by enclosing them in a larger ML cage, creating host-in-host complexes.
- The macrocyclic hosts, like cyclotriveratrylene and calix[8]arene, benefit from enhanced orientations which boost their ability to recognize other molecules.
- The structural analysis through X-ray techniques allows for observation of how these hosts encapsulate guest molecules within the highly crystalline ML cage.
Article Abstract
This study reports a method for enhancing the functions and properties of traditional organic macrocyclic hosts by fully encapsulating them within a large ML cage to form host-in-host complexes. Within the cage host, the macrocyclic organic hosts with electron-rich aromatic rings, such as cyclotriveratrylene and calix[8]arene, adopt specific orientations enhancing their inherent molecular recognition abilities. Due to the high crystallinity of the ML cage, the guest encapsulation behavior of the host-in-host complexes can be observed by X-ray structural analysis.
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Article Synopsis
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